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- W2078531660 abstract "Abstract A series of bis-[dimethyl(phenyl)silylmethyl] platinum(II) complexes cis-Pt(CH2SiMe2Ph)2L2 and Pt(CH2SiMe2Ph)2(BiL) with mono- and bidentate tertiary phosphine ligands {L = PMe3, PEt3, PMe2Ph, PMePh2, PPh3, P(4-C6H4CH3)3, PPh2(2-C6H4CH3) PPh2(2-C6H4CF3); BiL = bis(diphenylphosphino)methane [dppm], 1,2-bis(diphenylphosphino)ethane [dppe], 1,3-bis(diphenylphosphino)propane [dppp], 1,4-bis(diphenylphosphino)butane [dppb], 1,1′-bis(diphenylphosphino)ferrocene [dppf]} has been synthesized by metathetical displacement of the dialkene from Pt(CH2SiMe2Ph)2(cod) or Pt(CH2SiMe2Ph)2 (nbd) {cod = cycloocta-1,5-diene; nbd = bicyclo[2.2.1]hepta-2,5-diene}. These new complexes have been characterized by IR and NMR [1H, 13C and 31P] spectroscopy and their notable features are discussed. The sila-neophyl [sila-neophyl = dimethyl(phenyl)silylmethyl] ligand exhibits a weaker NMR trans-influence than its carbon analogue." @default.
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- W2078531660 date "1989-01-01" @default.
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- W2078531660 title "Synthesis and spectroscopic characteristics of bis-[dimethyl(phenyl)silylmethyl]platinum(II) complexes with nitrogen donor ligands" @default.
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- W2078531660 doi "https://doi.org/10.1016/s0277-5387(00)86379-2" @default.
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