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- W2078537231 abstract "$k$-odd electrostatic crystal-field parameters (${ensuremath{beta}}_{q}^{k}$) involved in the Judd-Ofelt theory of electronic transitions within the $4{f}^{n}$ configuration are computed including contributions of point charges, consistent dipoles, and quadrupoles induced in a crystalline lattice (calculated and experimental intensity parameters ${ensuremath{Omega}}_{ensuremath{lambda}}$ are compared). The coefficients (${ensuremath{gamma}}_{q}^{k}$) involved in the pseudo-multipolar-field theory are also computed for 14 rare-earth or rare-earth---doped compounds (i.e., for LiY${mathrm{F}}_{4}$: ${mathrm{Nd}}^{3+}$, YOBr, and YOCl: ${mathrm{Eu}}^{3+}$; BaFCl and SrFCl: ${mathrm{Sm}}^{2+}$; BaTi${mathrm{O}}_{3}$: ${mathrm{Eu}}^{3+}$, NdAl${mathrm{O}}_{3}$, and LaAl${mathrm{O}}_{3}$: ${mathrm{Eu}}^{3+}$; ${mathrm{Nd}}_{2}$${mathrm{O}}_{3}$, ${mathrm{Nd}}_{2}$${mathrm{O}}_{2}$S, La${mathrm{F}}_{3}$, and La${mathrm{Cl}}_{3}$: ${mathrm{Nd}}^{3+}$; ${mathrm{Y}}_{2}$${mathrm{O}}_{3}$ and K${mathrm{Y}}_{3}$${mathrm{F}}_{10}$: ${mathrm{Eu}}^{3+}$). The contribution of ${ensuremath{gamma}}_{q}^{k}$ to transition rates is evaluated for the $^{5}D_{0}ensuremath{rightarrow}^{7}F_{4}$ and $^{5}D_{0}ensuremath{rightarrow}^{7}F_{2}$ transitions of ${mathrm{Eu}}^{3+}$ in ${mathrm{Y}}_{2}$${mathrm{O}}_{3}$ and compared with the experimental values." @default.
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- W2078537231 date "1983-06-15" @default.
- W2078537231 modified "2023-09-23" @default.
- W2078537231 title "Electrostatic crystal-field contributions in rare-earth compounds with consistent multipolar effects. II. Contribution to<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>k</mml:mi></mml:math>-odd parameters (transition probabilities)" @default.
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- W2078537231 doi "https://doi.org/10.1103/physrevb.27.7386" @default.
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