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- W2078540992 abstract "The purpose of this study was to correlate the photocatalytic degradation of water contaminants with the adsorption phenomena, taking both the equilibrium state and kinetics into consideration. 1,2-Dichloroethane (DCE) was chosen as a test pollutant. The adsorption isotherm was found to follow the Langmuir model. The kinetics of adsorption were studied and interpreted as a mass transfer process. The kinetics of photocatalytic degradation were analysed with special attention given to the influence of the reactant concentration. A kinetic model is proposed, which includes mass transfer, leading to an apparent Langmuir-Hinshelwood equation for the degradation rate, even when the kinetics are controlled by mass transfer. The experimental results show an agreement with the model at concentrations above 0.5 mmol l−1, but at lower concentrations the rate is lower than expected, possibly due to a loss of DCE or hydroxyl radicals." @default.
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- W2078540992 date "1995-01-01" @default.
- W2078540992 modified "2023-09-30" @default.
- W2078540992 title "Adsorption properties of TiO2 related to the photocatalytic degradation of organic contaminants in water" @default.
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- W2078540992 doi "https://doi.org/10.1016/1010-6030(94)03900-f" @default.
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