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- W2078541223 abstract "A novel pyridine containing tetraazamacrocycle 3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(15),11,13-triene-3,6,9-triacetic acid ethyl ester (1) and its mononuclear Mn2+ complex (2) have been prepared. Pyridine induced the π–π stacking of [Mn1]2+ and provided donors for nonclassical CH…O hydrogen bonding as well. In the solid state of 2, the combination of π–π interactions and hydrogen bonding constructed a 3D crystal structure and thus formed pairs of interacting mononuclear complexes that mediated weak magnetic exchanges between the Mn2+ ions. Meanwhile, self-assembly of 2 dissociated in the aqueous solution, and the effect of pyridine on the nature of DNA binding with 2 have also been investigated." @default.
- W2078541223 created "2016-06-24" @default.
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- W2078541223 date "2012-07-01" @default.
- W2078541223 modified "2023-10-15" @default.
- W2078541223 title "A mononuclear Mn2+ complex based on a novel tris-(ethyl acetate) pendant-armed tetraazamacrocycle: Effect of pyridine on self-assembly and weak interactions" @default.
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- W2078541223 doi "https://doi.org/10.1016/j.inoche.2012.03.042" @default.
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