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- W2078541444 abstract "The vapor-liquid equilibria of three alcohol-alcohol binary mixtures (methanol-ethanol, methanol-1-propanol and ethanol-1-propanol) and three alcohol-water binary mixtures (methanol-water, ethanol-water and allyl alcohol-water) containing calcium chloride were measured at 298.15 K using a flow-type apparatus. The measured data of each ternary system were correlated by the use of a semi-empirical model proposed by Hála. It was found that the model with the optimal value of the exponent β = 5.0 in the electrostatic interaction term, originally given as 3/2 by Hála, gives reasonable prediction to all the systems in this study. Les équilibres liquide-vapeur de trois mélanges binaires alcool-alcool (méthanol, éthanol, méthanol-1-propanol et éthanol-1-propanol) et trois mélanges binaires alcool-eau (méthanol-eau, éthanol-eau et allyl acool-eau) contenant du chlorure de calcium, ont été mesurés à 298,15 K avec un appareillage de type écoulement. Les données mesurées de chaque système ternaire ont été corrélées au moyen d'un modèle semi-empirique proposé par Hala. On a trouvé que le modèle ayant la valeur d'exposant optimale β = 5,0 dans le terme d'interaction électrostatique, donné à l'origine comme étant 3/2 par Hala, prédit de maniére raisonnable tous les systèmes présentéd dans cette étude." @default.
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- W2078541444 date "1992-12-01" @default.
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- W2078541444 title "Effect of calcium chloride on vapor-liquid equilibria of alcohol-alcohol and alcohol-water binary systems" @default.
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- W2078541444 doi "https://doi.org/10.1002/cjce.5450700619" @default.
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