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- W2078541489 abstract "The solid-state structure of bis(2,3,4-trimethylpentadienyl)iron, Fe(2,3,4-C8H13)2, has been determined by single crystal X-ray diffraction. The space group is Ci1-P1 (No. 2) with unit cell parameters being a 9.442(3), b 11.212(3), c 7.743(3) Å, α 101.38(3), β 116.29(3), γ 89.77(2)°, and V 717.3(4) Å3 for Z = 2. Final agreement indices of R = 0.046 and Rw = 0.051 were obtained for the 1998 unique reflections judged to be above background. Even with substantially increased ligand-ligand repulsions relative to its isomorphous ruthenium analog, the complex has also been found to exist in a distorted gauche-eclipsed structure. The average FeC bond distance of 2.087(1) Å compares well with the value of 2.089(3) Å in Fe(2,4-C7H11)." @default.
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- W2078541489 date "1987-04-01" @default.
- W2078541489 modified "2023-09-26" @default.
- W2078541489 title "Solid-state structure of bis(2,3,4-trimethylpentadienyl)iron" @default.
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- W2078541489 doi "https://doi.org/10.1016/0022-328x(87)80311-x" @default.
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