FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078542455> ?p ?o ?g. }

• W2078542455 endingPage "19" @default.
• W2078542455 startingPage "1" @default.
• W2078542455 abstract "Data for the pK of cationic weak acids BH+ in binary mixed solvents have been collected and critically analyzed. This dissociation reaction is isoelectric, and electrostatic charging effects should have a minimal influence on the change of pK with solvent composition. Thus conditions are favorable for an examination of the effects of solute-solvent interactions on the dissociation reaction with little interference from electrostatic contributions. Standard Gibbs transfer energies derived from the change in pK were xamind, with the aid of solubility data, in terms of the contributions of the individual species. Comparisons were made with the corresponding quantities for the alkali chlorides and the results correlated with the aid of the activities of the two components of the solvent mixture. In solvents of which water was one component, it was possible to relate the transfer energy for hydrochloric acid to the activity of water alone, to a good approximation. At both extremes of the composition range, there are indications that preferential solvation can account for the “observed” differences in transfer energies of the ions BH+ and H+. The results therefore confirm the earlier conclusion that solute-solvent interactions, rather than electrostatic effects associated with the change in dielectric constant, are largely responsible for the changes of pK with composition of the solvent mixtures." @default.
• W2078542455 created "2016-06-24" @default.
• W2078542455 creator A5057804127 @default.
• W2078542455 date "1971-01-01" @default.
• W2078542455 modified "2023-10-02" @default.
• W2078542455 title "Solute-solvent interactions and acid-base dissociation in mixed solvent systems" @default.
• W2078542455 cites W1979825890 @default.
• W2078542455 cites W1993181676 @default.
• W2078542455 cites W1997308528 @default.
• W2078542455 cites W2001880621 @default.
• W2078542455 cites W2009145213 @default.
• W2078542455 cites W2019026877 @default.
• W2078542455 cites W2034858685 @default.
• W2078542455 cites W2035580137 @default.
• W2078542455 cites W2039276850 @default.
• W2078542455 cites W2051151510 @default.
• W2078542455 cites W2069082540 @default.
• W2078542455 cites W2085328588 @default.
• W2078542455 cites W2095053560 @default.
• W2078542455 cites W2153236895 @default.
• W2078542455 cites W2167083016 @default.
• W2078542455 cites W2314056909 @default.
• W2078542455 cites W2320369819 @default.
• W2078542455 cites W2320620634 @default.
• W2078542455 cites W2324677713 @default.
• W2078542455 cites W2326029939 @default.
• W2078542455 cites W2326990026 @default.
• W2078542455 cites W2327407800 @default.
• W2078542455 cites W2328455670 @default.
• W2078542455 cites W2328688031 @default.
• W2078542455 cites W2328953107 @default.
• W2078542455 cites W2329490514 @default.
• W2078542455 cites W2329929484 @default.
• W2078542455 cites W2330482679 @default.
• W2078542455 cites W2333359644 @default.
• W2078542455 cites W2334702016 @default.
• W2078542455 cites W4234710627 @default.
• W2078542455 doi "https://doi.org/10.1016/s0022-0728(71)80070-0" @default.
• W2078542455 hasPublicationYear "1971" @default.
• W2078542455 type Work @default.
• W2078542455 sameAs 2078542455 @default.
• W2078542455 citedByCount "81" @default.
• W2078542455 countsByYear W20785424552012 @default.
• W2078542455 countsByYear W20785424552013 @default.
• W2078542455 countsByYear W20785424552014 @default.
• W2078542455 countsByYear W20785424552015 @default.
• W2078542455 countsByYear W20785424552016 @default.
• W2078542455 countsByYear W20785424552018 @default.
• W2078542455 countsByYear W20785424552019 @default.
• W2078542455 countsByYear W20785424552021 @default.
• W2078542455 countsByYear W20785424552022 @default.
• W2078542455 crossrefType "journal-article" @default.
• W2078542455 hasAuthorship W2078542455A5057804127 @default.
• W2078542455 hasConcept C102931765 @default.
• W2078542455 hasConcept C121332964 @default.
• W2078542455 hasConcept C132439834 @default.
• W2078542455 hasConcept C146477669 @default.
• W2078542455 hasConcept C147789679 @default.
• W2078542455 hasConcept C148093993 @default.
• W2078542455 hasConcept C155574463 @default.
• W2078542455 hasConcept C170961132 @default.
• W2078542455 hasConcept C178790620 @default.
• W2078542455 hasConcept C183882617 @default.
• W2078542455 hasConcept C184651966 @default.
• W2078542455 hasConcept C185592680 @default.
• W2078542455 hasConcept C2780471494 @default.
• W2078542455 hasConcept C97355855 @default.
• W2078542455 hasConceptScore W2078542455C102931765 @default.
• W2078542455 hasConceptScore W2078542455C121332964 @default.
• W2078542455 hasConceptScore W2078542455C132439834 @default.
• W2078542455 hasConceptScore W2078542455C146477669 @default.
• W2078542455 hasConceptScore W2078542455C147789679 @default.
• W2078542455 hasConceptScore W2078542455C148093993 @default.
• W2078542455 hasConceptScore W2078542455C155574463 @default.
• W2078542455 hasConceptScore W2078542455C170961132 @default.
• W2078542455 hasConceptScore W2078542455C178790620 @default.
• W2078542455 hasConceptScore W2078542455C183882617 @default.
• W2078542455 hasConceptScore W2078542455C184651966 @default.
• W2078542455 hasConceptScore W2078542455C185592680 @default.
• W2078542455 hasConceptScore W2078542455C2780471494 @default.
• W2078542455 hasConceptScore W2078542455C97355855 @default.
• W2078542455 hasIssue "1" @default.
• W2078542455 hasLocation W20785424551 @default.
• W2078542455 hasOpenAccess W2078542455 @default.
• W2078542455 hasPrimaryLocation W20785424551 @default.
• W2078542455 hasRelatedWork W1986019010 @default.
• W2078542455 hasRelatedWork W2050186274 @default.
• W2078542455 hasRelatedWork W2318131592 @default.
• W2078542455 hasRelatedWork W2333395664 @default.
• W2078542455 hasRelatedWork W2557747266 @default.
• W2078542455 hasRelatedWork W2692966770 @default.
• W2078542455 hasRelatedWork W2952350678 @default.
• W2078542455 hasRelatedWork W3007322664 @default.
• W2078542455 hasRelatedWork W3185885805 @default.
• W2078542455 hasRelatedWork W4311791262 @default.
• W2078542455 hasVolume "29" @default.
• W2078542455 isParatext "false" @default.
• W2078542455 isRetracted "false" @default.

• next