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- W2078551480 abstract "Malaprade’s triperiodatotetracobaltate(III) heteropoly condensed acid, H3[Co4I3O18(OH2)6]·nH2O, was characterized by examination of its coordination derivatives with ammonia, ethylenediamine, glycinato, or L-alaninato ligands. It was concluded that the ion of parent acid and its derivatives, [Co4I3O18X6]n− (X6=(OH2)6, (NH3)6, en3, (OH2)4(gly), or (OH2)4(L-ala)), commonly have a hexol-like arrangement of four cobalt(III) octahedra so that the whole skeletons are based on the Anderson structure. The hexol-like configuration is chiral, this being demonstrated by the separation of two diastereomers of [Co4I3O18(OH2)4(L-ala)]4− ion." @default.
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- W2078551480 date "1973-07-01" @default.
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- W2078551480 title "Hexaammine, Tris(ethylenediamine), Glycinato, and L-Alaninato Complexes of a Triperiodatotetracobaltate(III) Condensed Anion" @default.
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- W2078551480 doi "https://doi.org/10.1246/bcsj.46.2145" @default.
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