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- W2078561142 abstract "Abstract A short and efficient synthesis of (+)-8-deoxyvernolepin 2 from (−)-α-santonin by functionalization of the angular methyl from a 6 β-alkoxy radical generated by reaction of the alcohol with diphenylselenium hydroxyacetate and 1,4-fragmentation of a γ-hydroxylstannane using hypervalent organoiodine reagents as the key steps, is described. The most important structural features of this compound, the δ- valerolactone cis-fused to ring B moiety and the angular vinyl group, are introduced in the same step." @default.
- W2078561142 created "2016-06-24" @default.
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- W2078561142 date "2010-08-20" @default.
- W2078561142 modified "2023-09-26" @default.
- W2078561142 title "ChemInform Abstract: Synthesis of (+)-8-Deoxyvernolepin." @default.
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- W2078561142 doi "https://doi.org/10.1002/chin.199346212" @default.
- W2078561142 hasPublicationYear "2010" @default.
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