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- W2078564578 abstract "Adding lignin to a reaction mixture of coal plus hydrogen-donor solvent promoted more extensive depolymerization of the coal at lower temperatures. Using lignin ≈ 43% of the organic portion of coal was liquefied at 300 °C under ≈ 1400 p.s.i. of hydrogen, compared with 5% under similar conditions without lignin. Thermal depolymerization of the lignin at relatively low temperatures is believed to form resonance-stabilized phenoxy radicals, which then attack the coal causing scission of aliphatic carbon-carbon bonds in the coal. This hypothesis is also in accord with the observation that using guaiacol as solvent further increases coal conversion (up to ≈ 80%) under similar conditions." @default.
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- W2078564578 date "1986-01-01" @default.
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- W2078564578 title "Coliquefaction of lignin and bituminous coal" @default.
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- W2078564578 doi "https://doi.org/10.1016/0016-2361(86)90148-1" @default.
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