Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078565057> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2078565057 endingPage "82" @default.
- W2078565057 startingPage "75" @default.
- W2078565057 abstract "The bonding of methyltrimethoxysilane (MTMS), a model for alkoxysilane primers and adhesion promoters, to a hydrated alumina cluster has been studied with density functional theory. The most probable site for formation of an aluminosiloxane bond is at a surface hydroxyl defect site, such as might exist at a step dislocation on a hydrated alumina surface rather than the more symmetric tuck-in site with pseudo-C3v symmetry on the (0 0 0 1) surface. The energetics of the step-growth polymerization reaction of MTMS has also been studied, and it is concluded that the oligomerization/polymerization reaction, which consumes water and releases methanol, is practically athermal. Thus, the polymerization reaction is primarily driven by entropic factors. At low coverage, chemisorbed alkoxysilanes will most likely be unevenly distributed as determined by the irregularity of the surface defects and as influenced by the relative humidity at the time of application. At high coverage, well-aged alkoxysilanes on metal or semi-metal oxide surfaces are probably best represented as polymerized (thermoset) resins that are chemically bonded to the substrate at most, if not all, accessible hydroxyl sites." @default.
- W2078565057 created "2016-06-24" @default.
- W2078565057 creator A5045824984 @default.
- W2078565057 creator A5051464355 @default.
- W2078565057 date "2001-10-01" @default.
- W2078565057 modified "2023-10-18" @default.
- W2078565057 title "A quantum mechanical study of the bonding of a silyl ester to hydrated alumina" @default.
- W2078565057 cites W1965752441 @default.
- W2078565057 cites W1967667153 @default.
- W2078565057 cites W1971536162 @default.
- W2078565057 cites W1976192082 @default.
- W2078565057 cites W1996374650 @default.
- W2078565057 cites W2001621568 @default.
- W2078565057 cites W2007436314 @default.
- W2078565057 cites W2008275871 @default.
- W2078565057 cites W2026229160 @default.
- W2078565057 cites W2030687437 @default.
- W2078565057 cites W2038533471 @default.
- W2078565057 cites W2047345727 @default.
- W2078565057 cites W2053529541 @default.
- W2078565057 cites W2077528747 @default.
- W2078565057 cites W2084869400 @default.
- W2078565057 cites W2086074462 @default.
- W2078565057 cites W2086957099 @default.
- W2078565057 cites W2327471162 @default.
- W2078565057 cites W102977407 @default.
- W2078565057 doi "https://doi.org/10.1016/s0039-6028(01)01371-1" @default.
- W2078565057 hasPublicationYear "2001" @default.
- W2078565057 type Work @default.
- W2078565057 sameAs 2078565057 @default.
- W2078565057 citedByCount "4" @default.
- W2078565057 countsByYear W20785650572015 @default.
- W2078565057 crossrefType "journal-article" @default.
- W2078565057 hasAuthorship W2078565057A5045824984 @default.
- W2078565057 hasAuthorship W2078565057A5051464355 @default.
- W2078565057 hasConcept C127413603 @default.
- W2078565057 hasConcept C161790260 @default.
- W2078565057 hasConcept C178790620 @default.
- W2078565057 hasConcept C185592680 @default.
- W2078565057 hasConcept C188027245 @default.
- W2078565057 hasConcept C192562407 @default.
- W2078565057 hasConcept C2779723377 @default.
- W2078565057 hasConcept C2780443040 @default.
- W2078565057 hasConcept C2781448156 @default.
- W2078565057 hasConcept C42360764 @default.
- W2078565057 hasConcept C44228677 @default.
- W2078565057 hasConcept C521977710 @default.
- W2078565057 hasConcept C5304478 @default.
- W2078565057 hasConcept C544153396 @default.
- W2078565057 hasConcept C75473681 @default.
- W2078565057 hasConcept C84416704 @default.
- W2078565057 hasConceptScore W2078565057C127413603 @default.
- W2078565057 hasConceptScore W2078565057C161790260 @default.
- W2078565057 hasConceptScore W2078565057C178790620 @default.
- W2078565057 hasConceptScore W2078565057C185592680 @default.
- W2078565057 hasConceptScore W2078565057C188027245 @default.
- W2078565057 hasConceptScore W2078565057C192562407 @default.
- W2078565057 hasConceptScore W2078565057C2779723377 @default.
- W2078565057 hasConceptScore W2078565057C2780443040 @default.
- W2078565057 hasConceptScore W2078565057C2781448156 @default.
- W2078565057 hasConceptScore W2078565057C42360764 @default.
- W2078565057 hasConceptScore W2078565057C44228677 @default.
- W2078565057 hasConceptScore W2078565057C521977710 @default.
- W2078565057 hasConceptScore W2078565057C5304478 @default.
- W2078565057 hasConceptScore W2078565057C544153396 @default.
- W2078565057 hasConceptScore W2078565057C75473681 @default.
- W2078565057 hasConceptScore W2078565057C84416704 @default.
- W2078565057 hasIssue "1-2" @default.
- W2078565057 hasLocation W20785650571 @default.
- W2078565057 hasOpenAccess W2078565057 @default.
- W2078565057 hasPrimaryLocation W20785650571 @default.
- W2078565057 hasRelatedWork W1592072547 @default.
- W2078565057 hasRelatedWork W1981159850 @default.
- W2078565057 hasRelatedWork W1995849362 @default.
- W2078565057 hasRelatedWork W2035012507 @default.
- W2078565057 hasRelatedWork W2059781191 @default.
- W2078565057 hasRelatedWork W2082644354 @default.
- W2078565057 hasRelatedWork W2089714952 @default.
- W2078565057 hasRelatedWork W2104544379 @default.
- W2078565057 hasRelatedWork W2165039731 @default.
- W2078565057 hasRelatedWork W2734899602 @default.
- W2078565057 hasVolume "492" @default.
- W2078565057 isParatext "false" @default.
- W2078565057 isRetracted "false" @default.
- W2078565057 magId "2078565057" @default.
- W2078565057 workType "article" @default.