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• W2078573776 abstract "A zinc(II) coordination polymer, [Zn4(o-bda)4(p-pbim)4] n (1) (p-pbim = 4-pyridylbenzimidazole, o-bda2− = o-phenylenediacetic acid dianion), has been synthesized by hydrothermal method and characterized by elemental analysis, IR, TG, photoluminescence and X-ray single crystal diffraction. Complex 1 crystallizes in a monoclinic system and space group P21 /n, with a = 14.231(3) Å, b = 16.257(4) Å, c = 16.794(4) Å, β = 100.262(1)°, and Z = 8; R 1 for 6475 observed reflections [I > 2σ(I)] was 0.0420. Complex 1 shows a bi-chain structure fabricated by the tetranuclear zinc unit. Two zinc(II) ions are five coordinate with distorted trigonal-bipyramid geometry; the other two zinc(II) ions are four coordinate with distorted tetrahedral geometry. Complex 1 builds the 1-D bi-chain structure with two different subrings A and B, which are 32-member and 14-member rings, respectively. There exists a 2-D supramolecular network linked by hydrogen-bonding interactions (2.695 and 2.807 Å). A 3-D supramolecular network is further constructed by non-covalent interactions between the 1-D bi-chain structure. The TG/DTG shows that the chain skeleton is thermally stable to 356°C. Blue fluorescent emission of the complex was determined at 404 nm in the solid state with short decay lifetime of 1.67 ns." @default.
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• W2078573776 date "2009-01-30" @default.
• W2078573776 modified "2023-09-25" @default.
• W2078573776 title "A zinc(II) coordination polymer, [Zn₄(<b> <i>o</i> </b>-bda)₄(<b> <i>p</i> </b>-pbim)₄]_{<b> <i>n</i> </b>}, with strong blue fluorescence" @default.
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• W2078573776 doi "https://doi.org/10.1080/00958970802379095" @default.
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