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• W2078581296 abstract "Amino acid-derived thioamides are prepared and evaluated as ligands in the rhodium-catalyzed asymmetric transfer hydrogenation of ketones in 2-propanol. It is found that increasing the steric bulk at the C-terminus of the ligand had a positive impact on both activity and selectivity in the reduction reaction. In order to find the optimum catalyst, a study is performed on a series of thioamide ligands having substituents of varying size." @default.
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• W2078581296 date "2009-11-01" @default.
• W2078581296 modified "2023-09-24" @default.
• W2078581296 title "Fine-tuning catalytic activity and selectivity—[Rh(amino acid thioamide)] complexes for efficient ketone reduction" @default.
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• W2078581296 doi "https://doi.org/10.1016/j.tetlet.2009.08.116" @default.
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