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• W2078585506 abstract "Branching ratios and absolute cross sections have been measured for the dissociative recombination of DCCCN+ and DCCCND+ using the CRYRING ion storage ring. In the case of DCCCN+ the dissociation yielding D + C3N and those leading to two fragments containing a pair of heavy atoms dominate, whereas pathways producing a fragment with three heavy atoms play only a minor role. Conversely, for DCCCND+, only those channels preserving the carbon chain or producing two fragments with a pair of heavy atoms each are detected. The cross sections of the reactions are very similar and can be fitted to the expressions σ = × 10-15E(eV)-1.05±0.02 cm2 and σ = × 10-15E(eV)-1.10±0.02 cm2 for DCCCN+ and DCCCND+, respectively. From these data, thermal reaction rates of k(T) = × 10-6(T/300 K)-0.60±0.02 cm3 s-1 and k(T) = × 10-6(T/300 K)-0.58±0.02 cm3 s-1 were calculated for DCCCN+ and DCCCND+, respectively. These rates and branching ratios are compared with those hitherto used in astrophysical models." @default.
• W2078585506 created "2016-06-24" @default.
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• W2078585506 date "2004-10-01" @default.
• W2078585506 modified "2023-10-03" @default.
• W2078585506 title "Dissociative Recombination of Nitrile Ions: DCCCN⁺and DCCCND⁺" @default.
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• W2078585506 doi "https://doi.org/10.1086/422335" @default.
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