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- W2078597880 abstract "Molecular dynamics (MD) simulations of four water-solvated DNA duplexes were used to generate a database of approximately 27000 dinucleotide conformations. Analyzing this database, we investigated the relationship between so-called BI-BII transitions and short-range interproton distances. Four H-H distances were found particularly sensitive to BI-BII transitions: internucleotide H1'(n)-H68(n+1), H2'(n)-H68(n+1), and H2(n)-H68(n+1), and intranucleotide H2(n)-H68(n). Determination of these distances using classical NOESY spectroscopy can thus provide valuable indications on the existence of BII substates, complementing the existing method based on (31)P chemical shifts and (31)P-(1)H spin-spin coupling constants." @default.
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- W2078597880 date "2004-02-01" @default.
- W2078597880 modified "2023-10-18" @default.
- W2078597880 title "Discrimination Between BI and BII Conformational Substates of B-DNA Based on Sugar-base Interproton Distances" @default.
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- W2078597880 doi "https://doi.org/10.1080/07391102.2004.10506942" @default.
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