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- W2078602693 abstract "Generation of dialkyl phosphonyl and thiophosphonyl radicals in the presence of 1,1-difluoroolefins furnishes regioadducts 1, thereby providing the first general synthesis of 2,2-disubstituted-1,1-difluorophosphonates and -phosphonothioates. Phosphinyl radicals and radicals derived from diarylphosphine oxide are shown to behave in an analogous manner. Addition of the same radicals onto a monosubstituted 1,1-difluoroolefin gives mainly the reverse regioadduct, thus demonstrating the complementarity of the new preparation with the synthetic methods available from the literature." @default.
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- W2078602693 date "1996-03-01" @default.
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- W2078602693 title "Simple and efficient synthesis of 2,2-disubstituted-1,1-difluorophosphonates and phosphonothioates" @default.
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- W2078602693 doi "https://doi.org/10.1016/0040-4039(96)00239-0" @default.
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