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- W2078607784 abstract "Abstract The pentacoordinated tellurium(IV) complexes [R2TeCl2· L] [R = C6H5 or p-CH3OC6H4; L = Ph3PSe, (p-MeC6H4)3PSe, Bu3PSe or Ph2P(Se)(CH2)2(Se)PPh2] were obtained by the reaction of R2TeCl2 with L under anhydrous conditions. The complexes have been characterized by spectral (IR, 1H NMR and 31P NMR) studies. The reaction of RTeCl3 and L, however, yields tellurium/selenium metal. 1J(31P-77Se) coupling constant data suggest complexation. In case of bidentate donor bases only one donor site is used in coordination. The complexes possess distorted octahedral geometry around a central tellurium atom which is surrounded by five groups and one vacant site occupied by a lone pair." @default.
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- W2078607784 date "1987-01-01" @default.
- W2078607784 modified "2023-09-27" @default.
- W2078607784 title "Pentacoordinated complexes of organotellurium(IV) halides with tertiary phosphine selenides" @default.
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- W2078607784 doi "https://doi.org/10.1016/s0277-5387(00)80792-5" @default.
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