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- W2078608976 abstract "Aus Trimethyl - und Triäthyl(methylen)phosphoran und Trimethyl(methylen)arsoran werden mit äquimolaren Mengen Äthylenoxid cyclische Alkoxy(tetraalkyl)phosphorane bzw.-arsorane (1,2λ5-Oxaphospholane bzw. -arsolane) erhalten. — Nach1H-, 13C-und 31P-NMR-spektroskopischen Studien bei variabler Temperatur kommt diesen Verbindungen trigonal-bipyramidale Struktur mit einer Alkylgruppe und einem Sauerstoffatom in dem axialen Positionen zu. Synthesis and Structure of Cyclic Alkoxy(tetraalkyl)phosphoranes and -arsoranes From the reaction of trimethyl and triethyl methylenephosphoranes and -arsoranes resp., (1,2λ5-oxaphospholanes or -arsolanes, resp.), are obtained. According to variable temperature 1H, 13C and 31P n. m. r. spectra, these compounds can be assigned a trigonal-bipyramidal structure, with an alkyl group and an oxygen atom in axial positions." @default.
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- W2078608976 date "1976-09-01" @default.
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- W2078608976 title "Darstellung und Struktur von cyclischen Alkoxy(tetraalkyl)‐phosphoranen und ‐arsoranen" @default.
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- W2078608976 doi "https://doi.org/10.1002/cber.19761090922" @default.
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