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- W2078616985 abstract "Our results indicate that small amounts of an oxide deposited on a stable metal surface can trigger a massive surface reconstruction under reaction conditions. In low-energy electron microscopy (LEEM) experiments, no reconstruction of Cu(111) is observed after chemisorbing oxygen or after reducing O/Cu(111) in a CO atmosphere. On the other hand, LEEM images taken in situ during the reduction of CeO2/CuO1-x/Cu(111) show a complex nonuniform transformation of the surface morphology. Ceria particles act as nucleation sites for the growth of copper microterraces once CuO1-x is reduced. Can this reconstructed surface be used to enhance the catalytic activity of inverse oxide/metal catalysts? Indeed, CeOx on reconstructed Cu(111) is an extremely active catalyst for the water-gas shift process (CO + H2O → H2 + CO2), with the Cu microterraces providing very efficient sites for the dissociation of water and subsequent reaction with CO." @default.
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- W2078616985 date "2012-03-08" @default.
- W2078616985 modified "2023-10-03" @default.
- W2078616985 title "Nanopattering in CeO<sub><i>x</i></sub>/Cu(111): A New Type of Surface Reconstruction and Enhancement of Catalytic Activity" @default.
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- W2078616985 doi "https://doi.org/10.1021/jz300159p" @default.
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