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- W2078644857 abstract "We demonstrate that commonly face-centered cubic (fcc) metallic nanowires can be stabilized in hexagonal structures even when their surface energy contribution is relatively small. With a modified electrochemical growth process, we have grown purely single-crystalline 4H silver nanowires (AgNWs) of diameters as large as 100 nm within nanoporous anodic alumina and polycarbonate templates. The growth process is not limited by the/Ag Nernst equilibrium potential, and time-resolved imaging with high-resolution transmission electron microscopy (TEM) indicates a kinematically new mechanism of nanowire growth. Most importantly, our experiments aim to separate the effects of confinement and growth conditions on the crystal structure of nanoscale systems." @default.
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- W2078644857 date "2008-02-14" @default.
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- W2078644857 title "Stabilizing High-Energy Crystal Structure in Silver Nanowires with Underpotential Electrochemistry" @default.
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- W2078644857 doi "https://doi.org/10.1021/jp7117967" @default.
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