FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078649209> ?p ?o ?g. }

• W2078649209 endingPage "12650" @default.
• W2078649209 startingPage "12641" @default.
• W2078649209 abstract "Mononuclear Cu complexes with a 1,10-phenanthroline-based ligand adsorbed onto an edge-plane graphite electrode act as electrocatalysts for the 4-electron reduction of O2 to H2O. A mechanism is proposed for the electrocatalytic O2 reduction that accounts for the observed redox and kinetic dependences on coordinating anions and proton donors in the buffer. Systematic increases of ligand electron-withdrawing properties and/or the steric demands near the Cu center increase the E0 of the Cu catalysts but decrease the rate of O2 reduction. The kinetic rate of O2 reduction at E0, reported as kinetic current divided by catalyst redox charge, decreases as E0 increases: from 16 s-1 measured at E0 in air-saturated solutions for adsorbed Cu(phen) to 0.4 s-1 for Cu(2,9-Et2-phen). The maximum value of E for which catalytic activity can be attained is estimated to be +350 mV vs NHE. Near E0, the kinetic current deviates from that expected if O2 binding were the sole rate-limiting step. This indicates that one or more of the electrochemical reduction steps are rate limiting at potentials near E0." @default.
• W2078649209 created "2016-06-24" @default.
• W2078649209 creator A5010115051 @default.
• W2078649209 creator A5021192261 @default.
• W2078649209 creator A5063243685 @default.
• W2078649209 creator A5089597733 @default.
• W2078649209 date "2007-12-01" @default.
• W2078649209 modified "2023-10-14" @default.
• W2078649209 title "Kinetic and Mechanistic Studies of the Electrocatalytic Reduction of O₂ to H₂O with Mononuclear Cu Complexes of Substituted 1,10-Phenanthrolines" @default.
• W2078649209 cites W1896715521 @default.
• W2078649209 cites W1976572795 @default.
• W2078649209 cites W1984184890 @default.
• W2078649209 cites W1986625209 @default.
• W2078649209 cites W2006636051 @default.
• W2078649209 cites W2018551035 @default.
• W2078649209 cites W2021784937 @default.
• W2078649209 cites W2022035827 @default.
• W2078649209 cites W2026853932 @default.
• W2078649209 cites W2028291957 @default.
• W2078649209 cites W2045554534 @default.
• W2078649209 cites W2072463598 @default.
• W2078649209 cites W2073218455 @default.
• W2078649209 cites W2077546664 @default.
• W2078649209 cites W2088316235 @default.
• W2078649209 cites W2109841355 @default.
• W2078649209 cites W2167091606 @default.
• W2078649209 cites W2316014077 @default.
• W2078649209 cites W2321752577 @default.
• W2078649209 cites W2952953177 @default.
• W2078649209 doi "https://doi.org/10.1021/jp076106z" @default.
• W2078649209 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18076134" @default.
• W2078649209 hasPublicationYear "2007" @default.
• W2078649209 type Work @default.
• W2078649209 sameAs 2078649209 @default.
• W2078649209 citedByCount "94" @default.
• W2078649209 countsByYear W20786492092012 @default.
• W2078649209 countsByYear W20786492092013 @default.
• W2078649209 countsByYear W20786492092014 @default.
• W2078649209 countsByYear W20786492092015 @default.
• W2078649209 countsByYear W20786492092016 @default.
• W2078649209 countsByYear W20786492092017 @default.
• W2078649209 countsByYear W20786492092018 @default.
• W2078649209 countsByYear W20786492092019 @default.
• W2078649209 countsByYear W20786492092020 @default.
• W2078649209 countsByYear W20786492092021 @default.
• W2078649209 countsByYear W20786492092022 @default.
• W2078649209 countsByYear W20786492092023 @default.
• W2078649209 crossrefType "journal-article" @default.
• W2078649209 hasAuthorship W2078649209A5010115051 @default.
• W2078649209 hasAuthorship W2078649209A5021192261 @default.
• W2078649209 hasAuthorship W2078649209A5063243685 @default.
• W2078649209 hasAuthorship W2078649209A5089597733 @default.
• W2078649209 hasConcept C116569031 @default.
• W2078649209 hasConcept C121332964 @default.
• W2078649209 hasConcept C123669783 @default.
• W2078649209 hasConcept C135889238 @default.
• W2078649209 hasConcept C147789679 @default.
• W2078649209 hasConcept C148898269 @default.
• W2078649209 hasConcept C150394285 @default.
• W2078649209 hasConcept C161790260 @default.
• W2078649209 hasConcept C170493617 @default.
• W2078649209 hasConcept C17525397 @default.
• W2078649209 hasConcept C178790620 @default.
• W2078649209 hasConcept C179104552 @default.
• W2078649209 hasConcept C185592680 @default.
• W2078649209 hasConcept C190463131 @default.
• W2078649209 hasConcept C201194858 @default.
• W2078649209 hasConcept C52859227 @default.
• W2078649209 hasConcept C55493867 @default.
• W2078649209 hasConcept C55904794 @default.
• W2078649209 hasConcept C57156300 @default.
• W2078649209 hasConcept C62520636 @default.
• W2078649209 hasConcept C71240020 @default.
• W2078649209 hasConceptScore W2078649209C116569031 @default.
• W2078649209 hasConceptScore W2078649209C121332964 @default.
• W2078649209 hasConceptScore W2078649209C123669783 @default.
• W2078649209 hasConceptScore W2078649209C135889238 @default.
• W2078649209 hasConceptScore W2078649209C147789679 @default.
• W2078649209 hasConceptScore W2078649209C148898269 @default.
• W2078649209 hasConceptScore W2078649209C150394285 @default.
• W2078649209 hasConceptScore W2078649209C161790260 @default.
• W2078649209 hasConceptScore W2078649209C170493617 @default.
• W2078649209 hasConceptScore W2078649209C17525397 @default.
• W2078649209 hasConceptScore W2078649209C178790620 @default.
• W2078649209 hasConceptScore W2078649209C179104552 @default.
• W2078649209 hasConceptScore W2078649209C185592680 @default.
• W2078649209 hasConceptScore W2078649209C190463131 @default.
• W2078649209 hasConceptScore W2078649209C201194858 @default.
• W2078649209 hasConceptScore W2078649209C52859227 @default.
• W2078649209 hasConceptScore W2078649209C55493867 @default.
• W2078649209 hasConceptScore W2078649209C55904794 @default.
• W2078649209 hasConceptScore W2078649209C57156300 @default.
• W2078649209 hasConceptScore W2078649209C62520636 @default.
• W2078649209 hasConceptScore W2078649209C71240020 @default.
• W2078649209 hasIssue "49" @default.
• W2078649209 hasLocation W20786492091 @default.
• W2078649209 hasLocation W20786492092 @default.
• W2078649209 hasOpenAccess W2078649209 @default.

• next