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• W2078654237 abstract "Far-infrared spectroscopy (FIR) has been used to distinguish alumina phases boehmite, diaspore, gibbsite and bayerite. The pellets of samples were prepared by mixing alumina phases with polyethylene at a ratio of 1:50, and the spectra were recorded between 50 and 400 cm(-1). The spectrum of boehmite resembles that of diaspore in the 300-400 cm(-1) region. Boehmite has two characteristic FIR bands at 366 and 323 cm(-1), while diaspore has five at 354, 331, 250, 199 and 158 cm(-1). The spectrum of gibbsite resembles that of bayerite in the 230-300 cm(-1) region. Gibbsite shows three characteristic FIR bands at 371, 279 and 246 cm(-1), whereas bayerite shows six at 383, 345, 326, 296, 252 and 62 cm(-1). The overlapping bands were resolved, and the spectra were manipulated appropriately using band analysis techniques. The FIR spectra are in harmony with the FT-Raman spectra. Far-infrared spectroscopy allows the study and differentiation of the stretching of AlO4 units to characterize these four alumina phases. Far-IR spectroscopy complements the mid-IR and near-IR for distinguishing alumina phases in bauxites." @default.
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• W2078654237 date "2002-01-01" @default.
• W2078654237 modified "2023-10-03" @default.
• W2078654237 title "Far-infrared spectroscopy of alumina phases" @default.
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• W2078654237 doi "https://doi.org/10.1016/s1386-1425(01)00532-7" @default.
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