Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078657488> ?p ?o ?g. }
- W2078657488 endingPage "572" @default.
- W2078657488 startingPage "564" @default.
- W2078657488 abstract "Rate coefficients for the gas-phase reactions of Cl atoms with a series of unsaturated biogenic alcohols at 298 ± 3 K and 1 atm have been measured by the relative technique in an environmental chamber with in situ FTIR detection of reactants. The rate coefficients obtained using 1-butene and isobutene as reference compounds were (in units of 10−10 cm3 molecule−1 s−1): k1((E)-2-hexen-1-ol) = (3.49 ± 0.82), k2((E)-3-hexen-1-ol) = (3.42 ± 0.79), k3 ((Z)-3-hexen-1-ol) = (2.94 ± 0.72), k4((Z)-3-hepten-1-ol) = (3.80 ± 0.86) and k5((Z)-3-octen-1-ol) = (4.13 ± 0.68). This work constitutes the first kinetic study of the reactions cited above. The rate coefficients are compared with those for other unsaturated alcohols and a correlation between the reactivity of unsaturated alcohols toward Cl atoms and the energy of the HOMO of the unsaturated alcohols is presented. Based on the obtained results, the atmospheric lifetimes of the unsaturated alcohols have been estimated and possible atmospheric implications assessed." @default.
- W2078657488 created "2016-06-24" @default.
- W2078657488 creator A5012650708 @default.
- W2078657488 creator A5036446195 @default.
- W2078657488 creator A5074594564 @default.
- W2078657488 creator A5074782074 @default.
- W2078657488 creator A5076667113 @default.
- W2078657488 date "2014-09-01" @default.
- W2078657488 modified "2023-10-06" @default.
- W2078657488 title "Rate coefficients at 298 K and 1 atm for the tropospheric degradation of a series of C6, C7 and C8 biogenic unsaturated alcohols initiated by Cl atoms" @default.
- W2078657488 cites W1593655292 @default.
- W2078657488 cites W1968729900 @default.
- W2078657488 cites W1969834329 @default.
- W2078657488 cites W1974781315 @default.
- W2078657488 cites W1978996065 @default.
- W2078657488 cites W1979617222 @default.
- W2078657488 cites W1980916691 @default.
- W2078657488 cites W1981984990 @default.
- W2078657488 cites W1987553937 @default.
- W2078657488 cites W1991975801 @default.
- W2078657488 cites W1994831894 @default.
- W2078657488 cites W1997304190 @default.
- W2078657488 cites W1999012713 @default.
- W2078657488 cites W2002106487 @default.
- W2078657488 cites W200676708 @default.
- W2078657488 cites W2008026474 @default.
- W2078657488 cites W2012349632 @default.
- W2078657488 cites W2015573856 @default.
- W2078657488 cites W2018139061 @default.
- W2078657488 cites W2022204029 @default.
- W2078657488 cites W2023588006 @default.
- W2078657488 cites W2028116960 @default.
- W2078657488 cites W2028161674 @default.
- W2078657488 cites W2031065765 @default.
- W2078657488 cites W2032139549 @default.
- W2078657488 cites W2033374623 @default.
- W2078657488 cites W2034445813 @default.
- W2078657488 cites W2035364580 @default.
- W2078657488 cites W2041032898 @default.
- W2078657488 cites W2044724516 @default.
- W2078657488 cites W2050772174 @default.
- W2078657488 cites W2053977647 @default.
- W2078657488 cites W2058024197 @default.
- W2078657488 cites W2060334213 @default.
- W2078657488 cites W2067209936 @default.
- W2078657488 cites W2071108778 @default.
- W2078657488 cites W2071407676 @default.
- W2078657488 cites W2090259365 @default.
- W2078657488 cites W2091501238 @default.
- W2078657488 cites W2095535725 @default.
- W2078657488 cites W2098911398 @default.
- W2078657488 cites W2104313243 @default.
- W2078657488 cites W2107842672 @default.
- W2078657488 cites W2114756882 @default.
- W2078657488 cites W2119874172 @default.
- W2078657488 cites W2129490531 @default.
- W2078657488 cites W2136938528 @default.
- W2078657488 cites W2139980392 @default.
- W2078657488 cites W2148967073 @default.
- W2078657488 cites W2168304530 @default.
- W2078657488 cites W2169494585 @default.
- W2078657488 cites W2317006727 @default.
- W2078657488 cites W2951697125 @default.
- W2078657488 cites W2094378527 @default.
- W2078657488 doi "https://doi.org/10.1016/j.atmosenv.2014.05.050" @default.
- W2078657488 hasPublicationYear "2014" @default.
- W2078657488 type Work @default.
- W2078657488 sameAs 2078657488 @default.
- W2078657488 citedByCount "7" @default.
- W2078657488 countsByYear W20786574882015 @default.
- W2078657488 countsByYear W20786574882016 @default.
- W2078657488 countsByYear W20786574882020 @default.
- W2078657488 countsByYear W20786574882021 @default.
- W2078657488 countsByYear W20786574882022 @default.
- W2078657488 crossrefType "journal-article" @default.
- W2078657488 hasAuthorship W2078657488A5012650708 @default.
- W2078657488 hasAuthorship W2078657488A5036446195 @default.
- W2078657488 hasAuthorship W2078657488A5074594564 @default.
- W2078657488 hasAuthorship W2078657488A5074782074 @default.
- W2078657488 hasAuthorship W2078657488A5076667113 @default.
- W2078657488 hasBestOaLocation W20786574882 @default.
- W2078657488 hasConcept C113196181 @default.
- W2078657488 hasConcept C121332964 @default.
- W2078657488 hasConcept C135889238 @default.
- W2078657488 hasConcept C142724271 @default.
- W2078657488 hasConcept C148898269 @default.
- W2078657488 hasConcept C153294291 @default.
- W2078657488 hasConcept C160892712 @default.
- W2078657488 hasConcept C178790620 @default.
- W2078657488 hasConcept C185592680 @default.
- W2078657488 hasConcept C204787440 @default.
- W2078657488 hasConcept C2776910235 @default.
- W2078657488 hasConcept C32909587 @default.
- W2078657488 hasConcept C62520636 @default.
- W2078657488 hasConcept C71924100 @default.
- W2078657488 hasConcept C9075549 @default.
- W2078657488 hasConcept C93391505 @default.
- W2078657488 hasConceptScore W2078657488C113196181 @default.