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- W2078663902 abstract "4,7-Bis(chlorosulphophenyl)-1,10-phenanthroline-2,9-dicarboxylic acid (BCPDA) is proposed as a simple, highly sensitive and specific reagent for the ultrasensitive determination of Eu3+ with microsecond time-resolved spectrofluorimetry. The optimum reaction pH was 9.0 in a glycine buffer. Detection limit for Eu3+ was 3 × 10–13 mol l–1. No major interferences from other metals were found when the interferent was present in a 500-fold molar excess. Negative interference was observed at high (>1 × 10–3 mol l–1) concentrations of Fe3+ and Ca2+ presumably through the formation of non-fluorescent complexes with BCPDA." @default.
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- W2078663902 date "1991-01-01" @default.
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- W2078663902 title "Ultrasensitive determination of europium using microsecond time-resolved spectrofluorimetry" @default.
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- W2078663902 doi "https://doi.org/10.1039/an9911600627" @default.
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