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- W2078669743 abstract "The effect of pressure on structural relaxations in poly(propylene oxide) (PPO; MW = 4000) near the glass transition has been determined using photon correlation spectroscopy. Experimental results are reported for pressures ranging from 2.5 to 3.9 kbar at 253 K. The structural relaxation exhibits two distinct processes separated by ∼3 orders of magnitude in time. This observation is consistent with results of dielectric relaxation studies of PPO. The faster relaxation is associated with local segmental motions important in the glass−rubber transition. The mean relaxation time for the faster process exhibits an exponential dependence on pressure." @default.
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- W2078669743 date "1997-04-01" @default.
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- W2078669743 title "Pressure-Dependent Photon Correlation Spectroscopic Investigation of Poly(propylene oxide) near the Glass Transition" @default.
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- W2078669743 doi "https://doi.org/10.1021/ma960408+" @default.
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