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- W2078673586 abstract "This work reports experimental kinetic data of solvent-free glycerolysis of olive oil using a commercial immobilized lipase (Novozym 435) under the influence of ultrasound irradiation. The experiments were performed in a mechanically stirred reactor under ultrasound irradiation, evaluating the effects of temperature (50–70 °C), enzyme concentration (2.5–10 wt%) and glycerol to oil molar ratio (0.8:1–3:1). Results show that ultrasound-assisted lipase-catalyzed glycerolysis might be a potential alternative route to conventional methods, as high contents of reaction products, especially monoglycerides, were achieved at mild irradiation power supply (∼130 W) and temperature, in a relatively short reaction time (2 h) and low enzyme content (7.5 wt%). To completeness, two simplified kinetic modeling approaches, based on the ordered-sequential bi bi mechanism and reaction stoichiometry, were employed to represent the experimental data, thus allowing a better understanding of the reaction kinetics." @default.
- W2078673586 created "2016-06-24" @default.
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- W2078673586 date "2012-05-01" @default.
- W2078673586 modified "2023-10-14" @default.
- W2078673586 title "Kinetics of ultrasound-assisted lipase-catalyzed glycerolysis of olive oil in solvent-free system" @default.
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- W2078673586 doi "https://doi.org/10.1016/j.ultsonch.2011.09.005" @default.
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