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• W2078684006 abstract "Random DNA damage via the autoxidation of sulfite is observed to be mediated by micromolar concentrations of copper(II) and iron(III) metallodrug complexes. Importantly, these results are in contrast to observations made for nickel(II) complexes, where guanine-specific modification of DNA was observed. While the exact mechanism is not known, alcohol-quenching studies suggest the possible formation of sulfuroxyl radicals (SO 3 − , SO 5 − ). Furthermore, these complexes are also observed to be effective catalysts for lipid oxidation. This study represents the first observation of DNA and lipid damage by sulfite and copper(II) and iron(III) coordination compounds and may lend insight to the biological toxicity of these transition metals." @default.
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• W2078684006 date "1998-07-01" @default.
• W2078684006 modified "2023-09-26" @default.
• W2078684006 title "Metallodrug complexes that mediate DNA and lipid damage via sulfite autoxidation: copper(II) famotidine and iron(III) bis(salicyglycine)" @default.
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• W2078684006 doi "https://doi.org/10.1016/s0020-1693(97)06179-3" @default.
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