Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078691704> ?p ?o ?g. }
- W2078691704 endingPage "32" @default.
- W2078691704 startingPage "25" @default.
- W2078691704 abstract "Two heterobimetallic cluster compounds [MOS3Cu3(4-pic)6]·Br (M=Mo, W) with cationic cluster skeleton and halide anion Br− synthesized by the reaction of (NH4)2MOS3, CuBr and 4-picoline (4-pic) are presented. Their structures have been crystallographically determined and such nest-shaped cationic clusters, obtained for the first time, are interesting in comparison with the analogical nest-shaped clusters with a neutral skeleton or anionic skeleton. The non-linear optical (NLO) properties of these two clusters are investigated with an 8 ns pulsed laser at 532 nm. These two clusters exhibit large optical limiting abilities with limiting thresholds Fth=0.18 J cm−2 (1) and Fth=0.15 J cm−2 (2), respectively. Both compounds show strong third-order NLO absorption effects (α2-value of 1.6×10−10 m W−1 (1), 2.8×10−10 m W−1 (2)) and self-focusing performance (n2-value of 4.56×10−11 esu (1), 4.62×10−11 esu (2)) in 3.86×10−4 mol dm−3 (1) and 8.89×10−4 mol dm−3 (2) DMF solution separately. The corresponding effective NLO susceptibilities χ(3) are 5.4×10−12 esu (1) and 5.5×10−12 esu (2) while the corresponding hyperpolarizabilities (γ(1)=2.51×10−31 esu and γ(2)=1.03×10−31 esu) are also reported." @default.
- W2078691704 created "2016-06-24" @default.
- W2078691704 creator A5008099421 @default.
- W2078691704 creator A5009855140 @default.
- W2078691704 creator A5019435965 @default.
- W2078691704 creator A5021488560 @default.
- W2078691704 creator A5056222697 @default.
- W2078691704 creator A5060020861 @default.
- W2078691704 creator A5074935915 @default.
- W2078691704 creator A5083592659 @default.
- W2078691704 date "2000-12-01" @default.
- W2078691704 modified "2023-09-24" @default.
- W2078691704 title "Two interesting heterobimetallic compounds [MOS3Cu3(4-pic)6]·Br (M=Mo, W) with cationic cluster: synthesis, structural characterization, non-linear response and large optical limiting properties" @default.
- W2078691704 cites W1615512140 @default.
- W2078691704 cites W1970282528 @default.
- W2078691704 cites W1980441141 @default.
- W2078691704 cites W1982205949 @default.
- W2078691704 cites W2002423115 @default.
- W2078691704 cites W2002896478 @default.
- W2078691704 cites W2008006191 @default.
- W2078691704 cites W2011004017 @default.
- W2078691704 cites W2018644086 @default.
- W2078691704 cites W2029146125 @default.
- W2078691704 cites W2031602781 @default.
- W2078691704 cites W2054894145 @default.
- W2078691704 cites W2063542690 @default.
- W2078691704 cites W2067256362 @default.
- W2078691704 cites W2075258605 @default.
- W2078691704 cites W2078803369 @default.
- W2078691704 cites W2079938039 @default.
- W2078691704 cites W2079962689 @default.
- W2078691704 cites W2089779704 @default.
- W2078691704 cites W2092886288 @default.
- W2078691704 cites W2093205660 @default.
- W2078691704 cites W2097578667 @default.
- W2078691704 cites W2111854179 @default.
- W2078691704 cites W2124178469 @default.
- W2078691704 cites W2125771483 @default.
- W2078691704 cites W2145218680 @default.
- W2078691704 cites W2145818582 @default.
- W2078691704 cites W2313486203 @default.
- W2078691704 cites W2949680301 @default.
- W2078691704 cites W2950115943 @default.
- W2078691704 cites W2950230371 @default.
- W2078691704 cites W2950369295 @default.
- W2078691704 cites W2950947698 @default.
- W2078691704 cites W2951523966 @default.
- W2078691704 cites W2952521480 @default.
- W2078691704 cites W2952564749 @default.
- W2078691704 cites W572406511 @default.
- W2078691704 doi "https://doi.org/10.1016/s0020-1693(00)00302-9" @default.
- W2078691704 hasPublicationYear "2000" @default.
- W2078691704 type Work @default.
- W2078691704 sameAs 2078691704 @default.
- W2078691704 citedByCount "19" @default.
- W2078691704 countsByYear W20786917042013 @default.
- W2078691704 countsByYear W20786917042014 @default.
- W2078691704 countsByYear W20786917042015 @default.
- W2078691704 countsByYear W20786917042016 @default.
- W2078691704 countsByYear W20786917042017 @default.
- W2078691704 crossrefType "journal-article" @default.
- W2078691704 hasAuthorship W2078691704A5008099421 @default.
- W2078691704 hasAuthorship W2078691704A5009855140 @default.
- W2078691704 hasAuthorship W2078691704A5019435965 @default.
- W2078691704 hasAuthorship W2078691704A5021488560 @default.
- W2078691704 hasAuthorship W2078691704A5056222697 @default.
- W2078691704 hasAuthorship W2078691704A5060020861 @default.
- W2078691704 hasAuthorship W2078691704A5074935915 @default.
- W2078691704 hasAuthorship W2078691704A5083592659 @default.
- W2078691704 hasConcept C113196181 @default.
- W2078691704 hasConcept C120665830 @default.
- W2078691704 hasConcept C121332964 @default.
- W2078691704 hasConcept C125287762 @default.
- W2078691704 hasConcept C127413603 @default.
- W2078691704 hasConcept C145148216 @default.
- W2078691704 hasConcept C164866538 @default.
- W2078691704 hasConcept C171560689 @default.
- W2078691704 hasConcept C178790620 @default.
- W2078691704 hasConcept C179104552 @default.
- W2078691704 hasConcept C183882617 @default.
- W2078691704 hasConcept C185592680 @default.
- W2078691704 hasConcept C188027245 @default.
- W2078691704 hasConcept C188198153 @default.
- W2078691704 hasConcept C199360897 @default.
- W2078691704 hasConcept C41008148 @default.
- W2078691704 hasConcept C71240020 @default.
- W2078691704 hasConcept C78519656 @default.
- W2078691704 hasConcept C8010536 @default.
- W2078691704 hasConceptScore W2078691704C113196181 @default.
- W2078691704 hasConceptScore W2078691704C120665830 @default.
- W2078691704 hasConceptScore W2078691704C121332964 @default.
- W2078691704 hasConceptScore W2078691704C125287762 @default.
- W2078691704 hasConceptScore W2078691704C127413603 @default.
- W2078691704 hasConceptScore W2078691704C145148216 @default.
- W2078691704 hasConceptScore W2078691704C164866538 @default.
- W2078691704 hasConceptScore W2078691704C171560689 @default.
- W2078691704 hasConceptScore W2078691704C178790620 @default.
- W2078691704 hasConceptScore W2078691704C179104552 @default.