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- W2078697690 abstract "Platinum(II) and palladium(II) complexes of chiral P−Cl functionalized bis-phosphino ortho-carbaborane are readily obtained from reactions of chiral bidentate phosphino carbaborane ligands rac-1,2-(PRCl)2(C2B10H10) with [MCl2(COD)] (M = Pd, Pt; COD = 1,5-cyclooctadiene) to give cis-rac-[MCl2{1,2-(PRCl)2(C2B10H10)}] (M = Pt, Pd; R = tBu, Ph, NEt2, NPh2). cis-rac-[MCl2{1,2-(PtBuCl)2(C2B10H10)}] [M = Pt (1), Pd (6)] decompose in solution in toluene or dichloromethane at room temperature over several weeks with formation of the corresponding dinuclear platinum and palladium complex with two nido-carbaboranyl phosphine ligands, (RP,RP,SP,SP)-[{M(7,8-{PtBuCl}2C2B9H10)(μ-Cl)}2] [M = Pt (2), Pd (7)], among other decomposition products." @default.
- W2078697690 created "2016-06-24" @default.
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- W2078697690 date "2009-08-06" @default.
- W2078697690 modified "2023-09-26" @default.
- W2078697690 title "Platinum(II) and Palladium(II) Complexes of Chiral P−Cl Functionalized Bis-phosphino <i>ortho</i>-Carbaboranes" @default.
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- W2078697690 doi "https://doi.org/10.1021/ic9011907" @default.
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