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- W2078700558 abstract "New scandium and yttrium complexes ScL2(bpzmp)(THF) {L = Cl (1); L = CH2Si(CH3)3 (3)}, YL2(bpzmp) {L = Cl (2); L = OTf (5)} and Y(CH2SiMe3)2(bpzmp)(THF) (4) bearing the heteroscorpionate bpzmp ligand {bpzmp = (3,5-tBu2-2-phenoxo)bis(3,5-Me2-pyrazol-1-yl)methane} have been synthesized and characterized by means of NMR and Mass spectroscopy. The tridentate monoanionic ligand resulted κ3-coordinated to the metal via the oxygen and both the sp2 nitrogen atoms of the heterocycles, producing complexes in CS symmetry. The behavior of 1–4 in ethylene polymerization was investigated after proper activation with different activating agents. Complex 4, in combination with the Brönsted or Lewis acids [PhNMe2H][B(C6F5)4] or [Ph3C][B(C6F5)4], produced linear high molecular weight polyethylene in good yield." @default.
- W2078700558 created "2016-06-24" @default.
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- W2078700558 date "2009-09-01" @default.
- W2078700558 modified "2023-10-11" @default.
- W2078700558 title "Scandium and yttrium complexes of a heteroscorpionate [N,N,O]-donor-set ligand: Synthesis, characterization and catalytic activity in ethylene polymerization" @default.
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- W2078700558 doi "https://doi.org/10.1016/j.ica.2009.01.020" @default.
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