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- W2078702128 abstract "The excess enthalpies of mixtures of 2,3-dimethylbutane+cyclo-octane have been measured at 288.15, 298.15, and 313.15 K with an isothermal displacement calorimeter. The excess volumes have been measured at the same temperatures with a dilution dilatometer. Vapour pressures of the mixtures have been measured at 298.15 K by a precise static vapour pressure technique. The excess Gibbs free energy, calculated at the three temperatures from the vapour pressure measurements and the temperature dependence of the excess enthalpies has a maximum of 184 J mol−1. The excess Gibbs free energy is independent of temperature, within experimental error, over the temperature range considered. The excess enthalpy has a maximum of 185 J mol−1 at 288.15 K. The enthalpies decrease with increase in temperature. The excess volume has a minimum of −0.63 cm3 mol−1 at 288.15 K and the volumes become more negative with increase in temperature. All the extrema are at a mole fraction of cyclo-octane of 0.47." @default.
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- W2078702128 date "1973-09-01" @default.
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- W2078702128 title "Excess Gibbs free energies, excess enthalpies, and excess volumes for 2,3-dimethylbutane+ cyclo-octane" @default.
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- W2078702128 doi "https://doi.org/10.1016/s0021-9614(73)80005-9" @default.
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