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- W2078702768 abstract "Metastable impact electron spectroscopy (MIES) in combination with UPS(HeI) and X-ray photoelectron spectroscopy was applied to study chemisorption of CO2 on Ca and CaO films at room temperature. Ca surfaces were prepared by evaporating Ca films (ca 20 nm thickness) on a clean Si(111) surface; information on the topological structure of the Ca film was obtained with scanning tunneling microscopy (STM). CaO films were produced by exposing Ca films to O2 or N2O. Ca surfaces exposed to CO2 become terminated by carbonate complexes (CO2−3) while features typical for (Ca–O) bonds are detected underneath the surface. A closed carbonate layer forms also when a CaO film is exposed to CO2. The strong reactivity of the CaO surface against CO2 is in agreement with recent results of cluster calculations." @default.
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- W2078702768 date "1998-11-01" @default.
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- W2078702768 title "CO2 chemisorption at Ca and CaO surfaces: a study with MIES, UPS(HeI) and XPS" @default.
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- W2078702768 doi "https://doi.org/10.1016/s0039-6028(98)00721-3" @default.
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