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- W2078702788 endingPage "9626" @default.
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- W2078702788 abstract "Stereoselective reduction of acyclic N-sulfinyl beta-amino ketones with (LiEt(3)BH) and Li(t-BuO)(3)AlH, respectively, gave anti- and syn-1,3-amino alcohols with excellent selectivity. A formal asymmetric synthesis of the hydroxy piperidine alkaloids (-)-pinidinol and (+)-epipinidinol from a common N-sulfinyl beta-amino ketone ketal precursor was developed. The pinidinol piperidine ring was formed via a novel acid-catalyzed cascade reaction of a N-sulfinylamino silyl protected alcohol ketal." @default.
- W2078702788 created "2016-06-24" @default.
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- W2078702788 date "2008-11-06" @default.
- W2078702788 modified "2023-10-10" @default.
- W2078702788 title "Asymmetric Synthesis of Acyclic 1,3-Amino Alcohols by Reduction of <i>N</i>-Sulfinyl β-Amino Ketones. Formal Synthesis of (−)-Pinidinol and (+)- Epipinidinol" @default.
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- W2078702788 doi "https://doi.org/10.1021/jo801653c" @default.
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