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- W2078708043 abstract "Abstract The enthalpies of solution of two samples of cesium chloride and one sample of rubidium chloride were measured in an LKB Solution Calorimeter. These results were combined with the selected enthalpies of dilution to derive the standard enthalpies of solution ΔH soln o . The result obtained for ΔH soln o (RbCl, c, 298.15 K) is (4064 ± 6) cal th mol −1 and the results obtained for ΔH soln o (CsCl, c, 298.15 K) are (4108 ± 7) cal th mol −1 from one sample and (4100 ± 7) cal th mol −1 from the other sample. A value of (4104 ± 7) cal th mol −1 is recommended for ΔH soln o (CsCl, c, 298.15 K). The result obtained for CsCl differs significantly from most previous measurements. A series of measurements of the enthalpy of solution of KCl in water were performed to check the reliability of the calorimetric system. The value obtained for ΔH soln o (KCl, c, 298.15 K) was (4119 ± 5) cal th mol −1 , in excellent agreement with the critically selected value. Based on the measured enthalpies of solution, the enthalpies of formation of crystalline CsCl, ΔH f o (CsCl, c, 298.15 K), and RbCl, ΔH f o (RbCl, c, 298.15 K) were derived to be −(105.710 ± 0.038) kcal th mol −1 and −(104.016 ± 0.038) kcal th mol −1 , respectively." @default.
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- W2078708043 date "1979-01-01" @default.
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- W2078708043 title "The enthalpies of solution and formation of the chlorides of cesium and rubidium" @default.
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- W2078708043 doi "https://doi.org/10.1016/0021-9614(79)90081-8" @default.
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