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- W2078709904 abstract "Abstract We have studied the structure and transport properties of ten (Nd 2 − x Zr x )Zr 2 O 7+ x /2 ( x = 0–1.27) solid solutions, which lie in the ZrO 2 –Nd 2 Zr 2 O 7 isomorphous miscibility range. Major attention has been focused on the pyrochlore-like (Nd 2 − x Zr x )Zr 2 O 7+ x /2 solid solutions with x = 0–0.78, which are thought to be potential interstitial oxide ion conductors. The X-ray and neutron diffraction results demonstrate that the (Nd 2 − x Zr x )Zr 2 O 7+ x /2 ( x = 0–1.27) solid solutions undergo an order–disorder (pyrochlore–defect fluorite) structural phase transition. The (Nd 2 − x Zr x )Zr 2 O 7+ x /2 ( x = 0.2–0.78) have the bulk conductivity, ∼(1.2–4) × 10 –3 S/cm at 750 °C, which is two orders of magnitude higher than that of the ordered pyrochlore Nd 2 Zr 2 O 7 . An attempt has been made to determine the interstitial oxygen content of (Nd 2 − x Zr x )Zr 2 O 7+ x /2 ( x = 0.2; 0.67) in a reducing atmosphere using thermogravimetry and mass spectrometry. It has been shown that no reduction occurs in the NdZrO system, where neodymium has only one oxidation state, 3+." @default.
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- W2078709904 date "2014-08-01" @default.
- W2078709904 modified "2023-10-01" @default.
- W2078709904 title "Oxide ion transport in (Nd2−xZrx)Zr2O7+δ electrolytes by an interstitial mechanism" @default.
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- W2078709904 doi "https://doi.org/10.1016/j.jallcom.2014.03.068" @default.
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