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- W2078734904 abstract "The title compound can be prepared in good yield by heating either [Ru4(μ-H)4(CO)12] or [Au2Ru4(μ3-H)2(CO)12(PPh3)2] with [AuMe(PPh3)] in toluene. The related compound [Au3Ru4(μ3-H)(μ-dppm)(CO)12(PPh3)] has also been prepared. Both trigoldtetraruthenium clusters undergo dynamic behaviour in solution, involving intramolecular rearrangement of the metal core, as revealed by variable temperature NMR studies. The crystal structure of [Au3Ru4(μ3-H)(CO)12(PPh3)3] has been established by an X-ray diffraction study. The metal atom core comprises a trigonal bipyramidal AuRu4 unit with two AuRu2 faces capped by gold atoms." @default.
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- W2078734904 date "1984-01-01" @default.
- W2078734904 modified "2023-10-17" @default.
- W2078734904 title "Synthesis and molecular structure of [Au3Ru4(μ3-H)(CO)12(PPh3)3]" @default.
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- W2078734904 doi "https://doi.org/10.1016/s0277-5387(00)88088-2" @default.
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