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- W2078743516 abstract "Inelastic neutron scattering has been employed in the study of the electronic properties of Pr3+ in PrBa2Cu3O7 (a semiconductor). The absence of any sharp, well-defined crystal field excitations at energies less than 150 meV is contrasted with data obtained for NdBa2Cu3O7 (a 92 K superconductor) and PrScO3 (an insulating perovskite). The absence of sharp crystal field transitions for PrBa2Cu3O7 is attributed to a broadening of these levels via an f-electron-CuO (planar)- electron interaction. It is suggested that this interaction is responsible for the absence of superconductivity in PrBa2Cu3O7. The absence of a superconducting transition in CmBa2Cu3O7 is used as supporting evidence for this hypothesis." @default.
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- W2078743516 date "1990-04-01" @default.
- W2078743516 modified "2023-09-27" @default.
- W2078743516 title "F-electron localization/delocalization phenomena in PrBa2Cu3O7 and CmBa2Cu3O7" @default.
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- W2078743516 doi "https://doi.org/10.1016/0921-4526(90)90299-a" @default.
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