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- W2078744583 abstract "Reactions of the Boron Hydrides B3H7 and B5H9 with the Unsaturated Boron-Nitrogen Compounds NBtBu2 and NB2tBu3 THF · B3H7 reacts with RB≡NR (1, R = tBu) to yield the μ-amino-diborane(6) B2H4R(NHR) (5), which crystallizes in the triclinic space group Pī. The reaction of B3H7 with the azadiboriridine NB2tBu3 (2, R = tBu) leads to the known NB2R3 · BH3 (4) and the novel (NB2R3)2B2H4 (6). Product 6 is considered to represent a diaza-arachno-octaborane derivative. The iminoborane 1 reacts with B5H9 in the presence of lutidine (L) to give the ionic product [L – BR = NHR][B9H14] (7); our earlier report on the formation of the aza-arachno-heptaborate [LH][NB6H8R2] has to be revised. The products from the reaction of B5H9 with NB2R3 are 4 and 6." @default.
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- W2078744583 date "1993-08-01" @default.
- W2078744583 modified "2023-09-24" @default.
- W2078744583 title "Reaktionen der Borhydride B3H7 und B5H9 mit den ungesättigten Bor-Stickstoff-Verbindungen NBtBu2 und NB2tBu3" @default.
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- W2078744583 doi "https://doi.org/10.1002/cber.19931260805" @default.
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