FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078746613> ?p ?o ?g. }

• W2078746613 endingPage "2687" @default.
• W2078746613 startingPage "2681" @default.
• W2078746613 abstract "Abstract The exchange of aliphatic amines with Cr(CO)6 in heptane occurs in two steps: a CO is lost forming a solvent-coordinated complex, Cr(CO)5(heptane), and then heptane is lost to form Cr(CO) 5(amine). The enthalpies of exchange of aliphatic amines (piperidine, n-butylamine, di-n-butylamine and tri-n-butylamine) with Cr(CO)6 have been determined in heptane at ambient temperatures. The enthalpies of reaction determined by photoacoustic calorimetry (PAC) include contributions from hydrogen-bond formation between free amine and the pentacarbonylamine chromium, 1. The enthalpy of hydrogen-bond formation was found to be about 4 kcal mol−1 and was determined from the temperature and concentration dependence of the amine NH chemical shifts of 1. The PAC values were corrected for hydrogen-bond formation contributions to obtain only the enthalpy of ligand-exchange (ΔH12). The ΔH12 was more endothermic for bulky amines, and this steric effect can be attributed to inhibition of CRN bond formation. These results, along with those in the literature, provide a detailed description of the energetics of each step of the ligand-exchange in both directions. The results suggest there is a continuum from an associative to a dissociative process for the displacement of heptane by amine that depends on the steric bulk of the amine." @default.
• W2078746613 created "2016-06-24" @default.
• W2078746613 creator A5086648451 @default.
• W2078746613 date "1989-01-01" @default.
• W2078746613 modified "2023-09-25" @default.
• W2078746613 title "Photoacoustic calorimetry studies of ligand-exchange of aliphatic amines with Cr(CO)6: Steric effects and hydrogen bonding" @default.
• W2078746613 cites W1963688013 @default.
• W2078746613 cites W1968414569 @default.
• W2078746613 cites W1977032642 @default.
• W2078746613 cites W1977437723 @default.
• W2078746613 cites W1984339947 @default.
• W2078746613 cites W1984553426 @default.
• W2078746613 cites W1985857706 @default.
• W2078746613 cites W1986818280 @default.
• W2078746613 cites W1987861166 @default.
• W2078746613 cites W1992869712 @default.
• W2078746613 cites W1999446616 @default.
• W2078746613 cites W2009582757 @default.
• W2078746613 cites W2020211817 @default.
• W2078746613 cites W2026572123 @default.
• W2078746613 cites W2041424891 @default.
• W2078746613 cites W2044814320 @default.
• W2078746613 cites W2048148794 @default.
• W2078746613 cites W2049622743 @default.
• W2078746613 cites W2072281119 @default.
• W2078746613 cites W2073005788 @default.
• W2078746613 cites W2073844260 @default.
• W2078746613 cites W2078647174 @default.
• W2078746613 cites W2079377928 @default.
• W2078746613 cites W2081257602 @default.
• W2078746613 cites W2085001192 @default.
• W2078746613 cites W2085998027 @default.
• W2078746613 cites W2088945994 @default.
• W2078746613 cites W2093959665 @default.
• W2078746613 cites W2157914833 @default.
• W2078746613 cites W2314253343 @default.
• W2078746613 cites W2314498672 @default.
• W2078746613 cites W2319455094 @default.
• W2078746613 cites W2569525354 @default.
• W2078746613 cites W2942767758 @default.
• W2078746613 cites W2949227105 @default.
• W2078746613 cites W2950203000 @default.
• W2078746613 cites W2951448898 @default.
• W2078746613 cites W3024030248 @default.
• W2078746613 cites W4238917285 @default.
• W2078746613 doi "https://doi.org/10.1016/s0277-5387(00)80439-8" @default.
• W2078746613 hasPublicationYear "1989" @default.
• W2078746613 type Work @default.
• W2078746613 sameAs 2078746613 @default.
• W2078746613 citedByCount "17" @default.
• W2078746613 countsByYear W20787466132023 @default.
• W2078746613 crossrefType "journal-article" @default.
• W2078746613 hasAuthorship W2078746613A5086648451 @default.
• W2078746613 hasConcept C112887158 @default.
• W2078746613 hasConcept C116569031 @default.
• W2078746613 hasConcept C120665830 @default.
• W2078746613 hasConcept C121332964 @default.
• W2078746613 hasConcept C170493617 @default.
• W2078746613 hasConcept C178790620 @default.
• W2078746613 hasConcept C185592680 @default.
• W2078746613 hasConcept C201194858 @default.
• W2078746613 hasConcept C202270520 @default.
• W2078746613 hasConcept C32909587 @default.
• W2078746613 hasConcept C512968161 @default.
• W2078746613 hasConcept C54932901 @default.
• W2078746613 hasConcept C55493867 @default.
• W2078746613 hasConcept C75473681 @default.
• W2078746613 hasConcept C97355855 @default.
• W2078746613 hasConceptScore W2078746613C112887158 @default.
• W2078746613 hasConceptScore W2078746613C116569031 @default.
• W2078746613 hasConceptScore W2078746613C120665830 @default.
• W2078746613 hasConceptScore W2078746613C121332964 @default.
• W2078746613 hasConceptScore W2078746613C170493617 @default.
• W2078746613 hasConceptScore W2078746613C178790620 @default.
• W2078746613 hasConceptScore W2078746613C185592680 @default.
• W2078746613 hasConceptScore W2078746613C201194858 @default.
• W2078746613 hasConceptScore W2078746613C202270520 @default.
• W2078746613 hasConceptScore W2078746613C32909587 @default.
• W2078746613 hasConceptScore W2078746613C512968161 @default.
• W2078746613 hasConceptScore W2078746613C54932901 @default.
• W2078746613 hasConceptScore W2078746613C55493867 @default.
• W2078746613 hasConceptScore W2078746613C75473681 @default.
• W2078746613 hasConceptScore W2078746613C97355855 @default.
• W2078746613 hasIssue "22" @default.
• W2078746613 hasLocation W20787466131 @default.
• W2078746613 hasOpenAccess W2078746613 @default.
• W2078746613 hasPrimaryLocation W20787466131 @default.
• W2078746613 hasRelatedWork W1994628229 @default.
• W2078746613 hasRelatedWork W2008073449 @default.
• W2078746613 hasRelatedWork W2084115979 @default.
• W2078746613 hasRelatedWork W2117757307 @default.
• W2078746613 hasRelatedWork W2324594399 @default.
• W2078746613 hasRelatedWork W2342748018 @default.
• W2078746613 hasRelatedWork W2344209642 @default.
• W2078746613 hasRelatedWork W2954462537 @default.
• W2078746613 hasRelatedWork W2463810949 @default.
• W2078746613 hasRelatedWork W2470468744 @default.
• W2078746613 hasVolume "8" @default.

• next