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• W2078752756 endingPage "100" @default.
• W2078752756 startingPage "92" @default.
• W2078752756 abstract "Two new copper(II) compounds of chloranilate and 2,2':6',2' '-terpyridine have been synthesized, and the structures have been solved by the single-crystal X-ray diffraction method. The crystal structure of [[Cu(2)(CA)(terpy)(2)][Cu(CA)(2)]](n)(1), where H(2)CA = chloranilic acid and terpy = 2,2':6',2' '-terpyridine, consists of two modules, the dimer unit [Cu(2)(CA)(terpy)(2)](2+) and the anionic mononuclear unit [Cu(CA)(2)](2)(-), forming an alternated chain. The chain is stabilized by semicoordinating and additional but efficient secondary bonding interactions. The crystal structure of [[Cu(2)(CA)(terpy)(2)(dmso)(2)][Cu(CA)(2)(dmso)(2)](EtOH)](n)(2), where dmso = dimethyl sulfoxide, consists of solvent molecules and two discrete modules, the dimer unit [Cu(2)(CA)(terpy)(2)(dmso)(2)](2+) and the anionic mononuclear unit [Cu(CA)(2)(dmso)(2)](2)(-). The dimer units form a layer by secondary bonding interactions, and the monomer units and ethanol molecules are introduced between the layers. The magnetic properties of 1 and 2 have been investigated in the temperature range 2.0-300 K. A weak ferromagnetic interaction was observed in 1, J(a) = 2.36 cm(-)(1) and zJ(b) = -0.68 cm(-)(1) while no exchange coupling was observed in 2." @default.
• W2078752756 created "2016-06-24" @default.
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• W2078752756 date "2003-12-05" @default.
• W2078752756 modified "2023-10-18" @default.
• W2078752756 title "Module-Based Assembly of Copper(II) Chloranilate Compounds: Syntheses, Crystal Structures, and Magnetic Properties of {[Cu₂(CA)(terpy)₂][Cu(CA)₂]}<i>_n</i> and {[Cu₂(CA)(terpy)₂(dmso)₂][Cu(CA)₂(dmso)₂](EtOH)}<i>_n</i> (H₂CA = Chloranilic Acid, terpy = 2,2‘:6‘,2‘ ‘-Terpyridine, dmso = Dimethyl Sulfoxide)" @default.
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• W2078752756 doi "https://doi.org/10.1021/ic035044y" @default.
• W2078752756 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14704057" @default.
• W2078752756 hasPublicationYear "2003" @default.
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