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- W2078753530 abstract "New cationic hydride complexes of rhodium(III) with PR3 and R-DAB ligands have been prepared and characterised. The tertiary phosphines employed were PPh3, PMePh2, PEt3 and the R-DAB ligands, (RN:CR′CR′:NR), c-Hex-DAB, Ph-DAB, NH2-DAB-(CH3,CH3). Hexacoordinate-dihydride complexes, characterized by 1H and 31P NMR, with stoichiometry [RhH2(R-DAB)(PR3)2]X were obtained. Compounds with other stoichiometries (R-DAB/PR3=1 or 2) are also possible. Preliminary studies of the catalytic activity in hydrogenation of olefins have been carried out." @default.
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- W2078753530 date "1986-09-01" @default.
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- W2078753530 title "Synthesis and characterization of new cationic hydride complexes of rhodium(III)" @default.
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- W2078753530 doi "https://doi.org/10.1016/s0020-1693(00)81322-5" @default.
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