FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078758301> ?p ?o ?g. }

• W2078758301 endingPage "440" @default.
• W2078758301 startingPage "433" @default.
• W2078758301 abstract "Nano-sized Fe(II, III) oxides with various Fe(II)/Fe(III) ratios were characterized and tested as catalysts for the oxidative degradation of phenol via Fenton-like reactions at neutral pH. Under conditions typically applied for wet peroxide oxidation, Fe(II) in magnetite is oxidized to Fe(III), successively converting the mineral into maghemite. The residual Fe(II) content in the catalyst core is of only minor benefit for the catalytic activity in phenol oxidation, i.e. magnetite is not superior to maghemite. Achievable reaction rates for phenol degradation appeared to be rather low, e.g. phenol half-life of about 12 h when 3 g L−1 magnetite and 5 g L−1 H2O2 were applied. Preceding surface-reduction of maghemite by NaBH4, leading to an over-stoichiometric Fe(II) content compared to magnetite, only enhanced the non-productive decomposition of H2O2 rather than the rate of phenol degradation. Reaction rates were shown to be relatively insensitive to catalyst concentration in the range of 1–10 g L−1, probably resulting from a scavenging of reactive species by the catalyst surface, whereby particle agglomeration seems to play a key role. Degradation experiments with various structurally distinct compounds were carried out, indicating a similar selectivity of the heterogeneous Fenton-like system to that known for oxidation with OH." @default.
• W2078758301 created "2016-06-24" @default.
• W2078758301 creator A5018054552 @default.
• W2078758301 creator A5041145302 @default.
• W2078758301 creator A5043611313 @default.
• W2078758301 date "2012-11-01" @default.
• W2078758301 modified "2023-09-29" @default.
• W2078758301 title "Nano-sized magnetic iron oxides as catalysts for heterogeneous Fenton-like reactions—Influence of Fe(II)/Fe(III) ratio on catalytic performance" @default.
• W2078758301 cites W1926950498 @default.
• W2078758301 cites W1964036477 @default.
• W2078758301 cites W1964509319 @default.
• W2078758301 cites W1966260043 @default.
• W2078758301 cites W1967596100 @default.
• W2078758301 cites W1968129749 @default.
• W2078758301 cites W1968774226 @default.
• W2078758301 cites W1979409292 @default.
• W2078758301 cites W1983228601 @default.
• W2078758301 cites W1983590413 @default.
• W2078758301 cites W1986530647 @default.
• W2078758301 cites W1986865794 @default.
• W2078758301 cites W1990455185 @default.
• W2078758301 cites W2009144164 @default.
• W2078758301 cites W2019688604 @default.
• W2078758301 cites W2021628155 @default.
• W2078758301 cites W2041978270 @default.
• W2078758301 cites W2050745240 @default.
• W2078758301 cites W2064769056 @default.
• W2078758301 cites W2069328662 @default.
• W2078758301 cites W2075559230 @default.
• W2078758301 cites W2077149030 @default.
• W2078758301 cites W2077452659 @default.
• W2078758301 cites W2082731532 @default.
• W2078758301 cites W2092284751 @default.
• W2078758301 cites W2095324001 @default.
• W2078758301 cites W2095390369 @default.
• W2078758301 cites W2106489547 @default.
• W2078758301 cites W2138565168 @default.
• W2078758301 cites W2143016116 @default.
• W2078758301 cites W2157835128 @default.
• W2078758301 cites W2169247501 @default.
• W2078758301 cites W2171692834 @default.
• W2078758301 cites W2188379506 @default.
• W2078758301 doi "https://doi.org/10.1016/j.jhazmat.2012.09.068" @default.
• W2078758301 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23098995" @default.
• W2078758301 hasPublicationYear "2012" @default.
• W2078758301 type Work @default.
• W2078758301 sameAs 2078758301 @default.
• W2078758301 citedByCount "223" @default.
• W2078758301 countsByYear W20787583012013 @default.
• W2078758301 countsByYear W20787583012014 @default.
• W2078758301 countsByYear W20787583012015 @default.
• W2078758301 countsByYear W20787583012016 @default.
• W2078758301 countsByYear W20787583012017 @default.
• W2078758301 countsByYear W20787583012018 @default.
• W2078758301 countsByYear W20787583012019 @default.
• W2078758301 countsByYear W20787583012020 @default.
• W2078758301 countsByYear W20787583012021 @default.
• W2078758301 countsByYear W20787583012022 @default.
• W2078758301 countsByYear W20787583012023 @default.
• W2078758301 crossrefType "journal-article" @default.
• W2078758301 hasAuthorship W2078758301A5018054552 @default.
• W2078758301 hasAuthorship W2078758301A5041145302 @default.
• W2078758301 hasAuthorship W2078758301A5043611313 @default.
• W2078758301 hasConcept C13965031 @default.
• W2078758301 hasConcept C161790260 @default.
• W2078758301 hasConcept C178790620 @default.
• W2078758301 hasConcept C179104552 @default.
• W2078758301 hasConcept C185592680 @default.
• W2078758301 hasConcept C191897082 @default.
• W2078758301 hasConcept C192562407 @default.
• W2078758301 hasConcept C199289684 @default.
• W2078758301 hasConcept C2777702071 @default.
• W2078758301 hasConcept C2777781897 @default.
• W2078758301 hasConcept C2779131772 @default.
• W2078758301 hasConcept C2779679103 @default.
• W2078758301 hasConcept C2780786144 @default.
• W2078758301 hasConcept C41008148 @default.
• W2078758301 hasConcept C533411734 @default.
• W2078758301 hasConcept C76155785 @default.
• W2078758301 hasConcept C77176794 @default.
• W2078758301 hasConceptScore W2078758301C13965031 @default.
• W2078758301 hasConceptScore W2078758301C161790260 @default.
• W2078758301 hasConceptScore W2078758301C178790620 @default.
• W2078758301 hasConceptScore W2078758301C179104552 @default.
• W2078758301 hasConceptScore W2078758301C185592680 @default.
• W2078758301 hasConceptScore W2078758301C191897082 @default.
• W2078758301 hasConceptScore W2078758301C192562407 @default.
• W2078758301 hasConceptScore W2078758301C199289684 @default.
• W2078758301 hasConceptScore W2078758301C2777702071 @default.
• W2078758301 hasConceptScore W2078758301C2777781897 @default.
• W2078758301 hasConceptScore W2078758301C2779131772 @default.
• W2078758301 hasConceptScore W2078758301C2779679103 @default.
• W2078758301 hasConceptScore W2078758301C2780786144 @default.
• W2078758301 hasConceptScore W2078758301C41008148 @default.
• W2078758301 hasConceptScore W2078758301C533411734 @default.
• W2078758301 hasConceptScore W2078758301C76155785 @default.
• W2078758301 hasConceptScore W2078758301C77176794 @default.
• W2078758301 hasLocation W20787583011 @default.

• next