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- W2078770108 endingPage "499" @default.
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- W2078770108 abstract "Abstract A molecular dynamics study of the electrophoresis of bottle‐brush polyelectrolytes (BPEs) through nanochannels is reported. The BPE molecules consist of a neutral backbone with charged side chains. For strong attractive interactions between the BPE and the wall, the BPE is being trapped on the channel surface. A stretching–shrinking migration of the BPE in a channel of radius 6 σ is observed at relatively strong electric fields. The stretching–shrinking transition is periodic for intermediate electric fields but not for stronger electric fields. The BPE also shows a transverse migration toward the wall at weak electric fields, while toward the center with further enhancing the electric field. For a channel with larger radius 12 σ , the BPE does not migrate in the stretching–shrinking manner. magnified image" @default.
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- W2078770108 date "2012-06-20" @default.
- W2078770108 modified "2023-10-10" @default.
- W2078770108 title "Electrophoresis of Bottle-Brush Polyelectrolytes in an Attractive Nanochannel" @default.
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- W2078770108 doi "https://doi.org/10.1002/mats.201100121" @default.
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