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- W2078805004 abstract "Optically active substituted ruthenocenes, (+)-RcCH(OH)Ph (I), (−)-RcCH(Me)Ph (II) and (+)-1-hydroxymethyl-2-methylruthenocene (VIII) react with molecular iodine to yield the corresponding iodoruthenocenium saltsIa, IIa, VIIIa with I3− anions. Reduction of these salts using, for example, NaBH4 regenerates the optically active starting compounds. Ruthenocenes with electron-withdrawing substituents (COMe, COPh, COOMe) remain intact when treated with I2, Fe(III), or Ce(IV). Asymmetric cyclopalladation of RcCH2NMe2 is described for the first time as the initial step of the reaction sequence leading to (+)-VIII." @default.
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- W2078805004 date "1996-11-01" @default.
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- W2078805004 title "Enantiomeric haloruthenocenium salts: synthesis of the first representatives with the use of asymmetric reduction and asymmetric cyclopalladation" @default.
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- W2078805004 doi "https://doi.org/10.1016/s0022-328x(96)06335-8" @default.
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