FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078805019> ?p ?o ?g. }

• W2078805019 endingPage "6776" @default.
• W2078805019 startingPage "6771" @default.
• W2078805019 abstract "Energy splittings resulting from anisotropy and exchange interactions in the dimer of single-molecule magnets [Mn4O3Cl4(O2CEt)3(py)3]2·8MeCN are determined for both an undeuterated and a partially deuterated sample using inelastic neutron scattering. The antiferromagnetic (AF) exchange coupling between the two Mn4 subunits strongly depends on their separation. The Cl···Cl distance between the two subunits can be modified either by exchanging the solvent of crystallization or by deuteration of the C−H···Cl hydrogen bonds. The exchange of acetonitrile for n-hexane leads to a five times greater shortening of the Cl···Cl separation than does full deuteration of all the hydrogen bonds. As a result, the AF exchange coupling constants between the subunits are 0.0073(4) and 0.0103(9) meV in the samples with acetonitrile and n-hexane solvent molecules, respectively, in the crystal structure. On the other hand, the effect of C−H···Cl deuteration on the AF exchange coupling is not detectable within the experimental accuracy of INS." @default.
• W2078805019 created "2016-06-24" @default.
• W2078805019 creator A5004308036 @default.
• W2078805019 creator A5019270627 @default.
• W2078805019 creator A5020464599 @default.
• W2078805019 creator A5027438204 @default.
• W2078805019 creator A5027439877 @default.
• W2078805019 creator A5048702084 @default.
• W2078805019 creator A5053561663 @default.
• W2078805019 creator A5075597926 @default.
• W2078805019 creator A5076657796 @default.
• W2078805019 date "2005-08-16" @default.
• W2078805019 modified "2023-10-11" @default.
• W2078805019 title "Direct Determination of the Anisotropy and Exchange Splittings in the Dimeric Single-Molecule Magnet [Mn₄O₃Cl₄(O₂CEt)₃(py)₃]₂·8MeCN by Inelastic Neutron Scattering" @default.
• W2078805019 cites W1582718027 @default.
• W2078805019 cites W1823409394 @default.
• W2078805019 cites W1964277385 @default.
• W2078805019 cites W1972335601 @default.
• W2078805019 cites W1973990675 @default.
• W2078805019 cites W1998163907 @default.
• W2078805019 cites W2000628866 @default.
• W2078805019 cites W2000638229 @default.
• W2078805019 cites W2002762653 @default.
• W2078805019 cites W2006038032 @default.
• W2078805019 cites W2037463866 @default.
• W2078805019 cites W2038409508 @default.
• W2078805019 cites W2041139408 @default.
• W2078805019 cites W2066478928 @default.
• W2078805019 cites W2080665513 @default.
• W2078805019 cites W2089740902 @default.
• W2078805019 cites W2091385430 @default.
• W2078805019 cites W2104199272 @default.
• W2078805019 cites W2146099614 @default.
• W2078805019 cites W2147575961 @default.
• W2078805019 cites W2161628917 @default.
• W2078805019 cites W2171503178 @default.
• W2078805019 cites W3098018236 @default.
• W2078805019 cites W3119304537 @default.
• W2078805019 doi "https://doi.org/10.1021/ic050764l" @default.
• W2078805019 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16156636" @default.
• W2078805019 hasPublicationYear "2005" @default.
• W2078805019 type Work @default.
• W2078805019 sameAs 2078805019 @default.
• W2078805019 citedByCount "9" @default.
• W2078805019 countsByYear W20788050192015 @default.
• W2078805019 countsByYear W20788050192018 @default.
• W2078805019 crossrefType "journal-article" @default.
• W2078805019 hasAuthorship W2078805019A5004308036 @default.
• W2078805019 hasAuthorship W2078805019A5019270627 @default.
• W2078805019 hasAuthorship W2078805019A5020464599 @default.
• W2078805019 hasAuthorship W2078805019A5027438204 @default.
• W2078805019 hasAuthorship W2078805019A5027439877 @default.
• W2078805019 hasAuthorship W2078805019A5048702084 @default.
• W2078805019 hasAuthorship W2078805019A5053561663 @default.
• W2078805019 hasAuthorship W2078805019A5075597926 @default.
• W2078805019 hasAuthorship W2078805019A5076657796 @default.
• W2078805019 hasConcept C104015590 @default.
• W2078805019 hasConcept C112887158 @default.
• W2078805019 hasConcept C113196181 @default.
• W2078805019 hasConcept C115624301 @default.
• W2078805019 hasConcept C120665830 @default.
• W2078805019 hasConcept C121332964 @default.
• W2078805019 hasConcept C155355069 @default.
• W2078805019 hasConcept C178790620 @default.
• W2078805019 hasConcept C184779094 @default.
• W2078805019 hasConcept C185592680 @default.
• W2078805019 hasConcept C191486275 @default.
• W2078805019 hasConcept C203036418 @default.
• W2078805019 hasConcept C26873012 @default.
• W2078805019 hasConcept C2777463227 @default.
• W2078805019 hasConcept C2779546866 @default.
• W2078805019 hasConcept C2780471494 @default.
• W2078805019 hasConcept C31198834 @default.
• W2078805019 hasConcept C32909587 @default.
• W2078805019 hasConcept C43617362 @default.
• W2078805019 hasConcept C58364064 @default.
• W2078805019 hasConcept C62520636 @default.
• W2078805019 hasConcept C8010536 @default.
• W2078805019 hasConcept C85725439 @default.
• W2078805019 hasConceptScore W2078805019C104015590 @default.
• W2078805019 hasConceptScore W2078805019C112887158 @default.
• W2078805019 hasConceptScore W2078805019C113196181 @default.
• W2078805019 hasConceptScore W2078805019C115624301 @default.
• W2078805019 hasConceptScore W2078805019C120665830 @default.
• W2078805019 hasConceptScore W2078805019C121332964 @default.
• W2078805019 hasConceptScore W2078805019C155355069 @default.
• W2078805019 hasConceptScore W2078805019C178790620 @default.
• W2078805019 hasConceptScore W2078805019C184779094 @default.
• W2078805019 hasConceptScore W2078805019C185592680 @default.
• W2078805019 hasConceptScore W2078805019C191486275 @default.
• W2078805019 hasConceptScore W2078805019C203036418 @default.
• W2078805019 hasConceptScore W2078805019C26873012 @default.
• W2078805019 hasConceptScore W2078805019C2777463227 @default.
• W2078805019 hasConceptScore W2078805019C2779546866 @default.
• W2078805019 hasConceptScore W2078805019C2780471494 @default.
• W2078805019 hasConceptScore W2078805019C31198834 @default.
• W2078805019 hasConceptScore W2078805019C32909587 @default.
• W2078805019 hasConceptScore W2078805019C43617362 @default.

• next