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- W2078809444 abstract "Standard thermodynamic functions of transfer of naphthalene and 2-naphthoic acid from water to (water + ethanol) mixtures at T=298.15 K have been determined from solubility measurements at different temperatures. Standard free energies of transfer of both naphthalene and 2-naphthoic acid showed decreasing tendency with the increasing x(EtOH), and the standard entropy and enthalpy of transfer exhibited a change of double peaks with x(EtOH). The ΔtrG0 of 2-naphthoic acid decreased more rapidly than that of naphthalene when x(EtOH) < 0.746 and lower than that of naphthalene when x(EtOH) >0.746 at T=298.15 K. The double peaks in the curves of standard entropy and enthalpy of transfer illustrated that the microstructure of the series of mixed solvents of (water + ethanol) underwent a variable process from ordered to disordered and then from disordered to ordered. The results mean that there is a relatively ordered structure near x(EtOH)=0.13 in the (water + ethanol) solutions besides the existence of a clathrate structure in the water-rich region." @default.
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- W2078809444 date "2003-09-01" @default.
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- W2078809444 title "Thermodynamics of transfer of naphthalene and 2-naphthoic acid from water to (water+ethanol) mixtures at T=298.15 K" @default.
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- W2078809444 doi "https://doi.org/10.1016/s0021-9614(03)00112-5" @default.
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