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- W2078810411 abstract "Abstract Efficient routes to chiral 4-hydroxy-5-hexenoic acids and lactones from d -gluconic acid-δ-lactone and l -mannonic acid-γ-lactone are described. In this approach, the starting lactones are converted to 2,6-dibromo compounds that readily undergo zinc mediated elimination to generate the terminal alkene group in concert with 2-deoxygenation. The integrity of the remaining stereocenters is preserved during the reaction. The related important pharmaceutical intermediates ( S )-3-hydroxy-4-pentenoic acid and ( S )-1,3-dihydroxy-4-pentene were also prepared from 2-deoxyribose via the corresponding aldonolactone." @default.
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- W2078810411 date "2001-03-01" @default.
- W2078810411 modified "2023-10-14" @default.
- W2078810411 title "Homochiral 4-hydroxy-5-hexenoic acids and their derivatives and homologues from carbohydrates" @default.
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- W2078810411 doi "https://doi.org/10.1016/s0957-4166(01)00053-2" @default.
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