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- W2078841478 abstract "Photofragmentation of (NO)n− (3≤n≤21) in the energy range 2.7–3.6 eV (350–460 nm) results in the production of (NO)m− with m≥2 and NO2−·(NO)m with 0≤m≤2. The photofragment yield spectra obtained for n=3–7 display a broad and structureless band profile with successive blue-shift with increase in the cluster size, indicating that (NO)3− behaves as a chromophoric core in the larger (NO)n−. The observed fragmentation patterns suggest that photoexcitation of the (NO)3− chromophore is followed by direct dissociation into (NO)2−, solvent evaporation to form (NO)m−, and/or intracluster reactions to produce NO2−." @default.
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- W2078841478 date "2002-10-01" @default.
- W2078841478 modified "2023-10-11" @default.
- W2078841478 title "Photochemistry of (NO)− as studied by photofragment mass spectrometry" @default.
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- W2078841478 doi "https://doi.org/10.1016/s1387-3806(02)00769-8" @default.
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