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- W2078873485 abstract "Reaction of [Pd(π-C3H5)Cl]2 with RNC (RNC = phenyl- and p-nitrophenyl-isocyanide) affords bridge-splitting product of the type [Pd(π-C3H5)(RNC)Cl]. The latter compounds react with SnCl2 and CsGeCl3 to give complexes containing PdSn and PdGe bonds [Pd(π-C3H5)(RNC)(MCl3)] (M=Sn, Ge). These derivatives were characterized mainly by i.r. and where possible by p.m.r. spectra. A tentative assignment of the palladium-metal stretching frequencies is reported. The bridge-splitting products [Pd(π-C3H5)(RNC)Cl] react with another molecule of isocyanide or triphenylphosphine to form 1-(aryl-immino)-3-butenyl derivatives, in which the isocyanide has inserted into the palladium-allyl σ bond." @default.
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- W2078873485 date "1971-03-01" @default.
- W2078873485 modified "2023-10-07" @default.
- W2078873485 title "Reactions of π-allyl-palladium(II) derivatives with isocyanides" @default.
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- W2078873485 doi "https://doi.org/10.1016/s0020-1693(00)95969-3" @default.
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