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- W2078883855 abstract "ZnO powders and epitaxial thin films were synthesized hydrothermally in aqueous solutions of zinc nitrate and ammonia at 150°C. Powder yield and particle size varied with changes in pH from 7 to 10.5. The films grew with a c-axis orientation on (1 1 1) MgAl2O4 substrates, with an out-of-plane orientation given by (111)s||(0001)Zn, and an in-plane orientation given by (112)s||(112̄0)Zn. Based on etching studies, the polarity of the films was determined to be zinc faced (0 0 0 1). The in-plane orientation relation corresponds to a 30° rotation of the close packed oxygen directions of the two respective structures. This rotation produces periodic, tetrahedrally coordinated Zn sites at the spinel/ZnO interface and facilitates the epitaxy of ZnO with only a small lattice strain. The crystal chemistry of the interfacial atomic layer that lies between the spinel and wurtzite is discussed in relation to cation coordination and charge balance." @default.
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- W2078883855 date "2003-11-01" @default.
- W2078883855 modified "2023-09-23" @default.
- W2078883855 title "Crystal chemistry of epitaxial ZnO on (111) MgAl2O4 produced by hydrothermal synthesis" @default.
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- W2078883855 doi "https://doi.org/10.1016/s0022-0248(03)01589-6" @default.
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